10) Observe the temperatures of water and wax at different situations and answer the following : \begin{tabular}{|c|c|c|c|c|c|} \hline \multirow{2}{*}{ Substance } & \multicolumn{5}{|c|}{ Situations } \\ \cline { 2 - 6 } & 1 & 2 & 3 & 4 & 5 \\ \hline Water & \( 75^{\circ} \mathrm{C} \) & \( 80^{\circ} \mathrm{C} \) & \( 85^{\circ} \mathrm{C} \) & \( 20 \mathrm{~K} \) & \( 30^{\circ} \mathrm{C} \) \\ \hline Wax & \( 43^{0} \mathrm{C} \) & \( 333 \mathrm{~K} \) & \( 85^{\circ} \mathrm{C} \) & \( 40^{\circ} \mathrm{C} \) & \( 30 \mathrm{~K} \) \\ \hline \end{tabular} a) In which situations heat flows from water to wax? b) In which situations heat flows from wax to water ? c) In which situations water and wax are in thermal equilibrium ?
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The cooling curve of pure wax material after heating is shown in the figure. It first cools from $A$ to $B$ and solidifies along $B D$. The ratio of $L / C$, if $L$ and $C$ are respective values of specific latent heat of fusion and specific heat capacity of the liquid wax is : (Assume rate of heat loss remain constant) (a) 40 (b) 80 (c) 100 (d) 20
Identify each of the following changes of state as melting, freezing, sublimation or deposition: a. Ice sculptures start breaking down as temperature rises above $0^{\circ} \mathrm{C}$ b. Ice forms on the strawberry plants on a cold wintry night. c. Water becomes solid at $0^{\circ} \mathrm{C}$. d. Dry ice on heating becomes gas.
Matter and Energy
Changes of State
At a certain temperature, the following reactions have the equilibrium constants as shown below: $$ \begin{aligned} \mathrm{S}(s)+\mathrm{O}_{2}(g) & \rightleftharpoons \mathrm{SO}_{2}(g) ; \quad K_{c}=5 \times 10^{52} \\ 2 \mathrm{~S}(s)+3 \mathrm{O}_{2}(g) & \rightleftharpoons 2 \mathrm{SO}_{3}(g) ; K_{c}=10^{29} \end{aligned} $$ What is the equilibrium constant $K_{c}$ for the reaction at the same temperature? $$ 2 \mathrm{SO}_{2}(g)+\mathrm{O}_{2}(g) \rightleftharpoons 2 \mathrm{SO}_{3}(g) $$ (a) $2.5 \times 10^{76}$ (b) $4 \times 10^{23}$ (c) $4 \times 10^{-77}$ (d) None of these
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