00:01
Hello students, we have some questions on stereochemistry.
00:04
In a part of first question, we have to write the name of this compound.
00:08
So primary chain will be the one which will contain triple and double bond.
00:13
Numbering will be like this 1 2 3 4 5 6 7 8.
00:19
So its word root will be oct.
00:22
Now if we look at the primary suffixes, it contains a double bond at 7th carbon.
00:31
It will be 7 -ene -1 -yne.
00:37
Now let's look at the prefixes.
00:40
So prefix will be 4 -bromo -4 -ethyl.
00:48
So complete name of the compound will be 4 -bromo -4 -ethyl -o -7 -ene -1 -yne.
01:11
This will be the correct iupac name.
01:14
Now let's look at b part.
01:15
In second question, we have a 2 -hexane derivative.
01:20
So 2 -hexane will have a triple bond at 2nd carbon.
01:24
So let's consider the hexane looks like this.
01:32
So this will be the structure.
01:35
Numbering will be like this.
01:40
Now at 4th carbon, we don't have any hydrogens.
01:45
We have two alkyl groups.
01:48
First is a methyl group and second is a cyclopropyl group.
01:54
We have been told that stereochemistry around this 4th chiral center is s.
02:00
So we will have to draw these methyl and cyclopropyl groups above and below respectively.
02:07
So let's calculate stereochemistry around 4th carbon.
02:13
Here we have a carbon atom that is connected to three carbon atoms.
02:18
Hence, its priority will be 1.
02:20
I am assigning these priorities according to the ip rules.
02:24
Now here we have a methyl group whose priority will be 4.
02:31
Now let's compare the other two groups.
02:33
This carbon atom is linked to two carbon atoms because this is a part of cyclopropyl group.
02:39
Whereas this is ethyl group.
02:41
This carbon is connected to only one carbon atom.
02:44
Hence this will have a lower priority and this will have a higher priority.
02:50
Now for making this configuration s, the rotation must go in an clockwise direction.
03:01
So this 4th priority group must be above the plane.
03:07
Now the priority of other three groups will be like this.
03:12
So this rotation will be s...