15) A particular first-order reaction has a rate constant of 1.35 × 10^2 s^-1 at 25.0°C. What is the magnitude of k at 75.0°C if Ea = 85.6 kJ/mol?
16) A reaction is found to have an activation energy of 108 kJ/mol. If the rate constant for this reaction is 4.60 × 10^-6 s^-1 at -1.85 ºC, what is the rate constant at 90.85 ºC?