2. For the oxidation of Pb, U, and Al with 1 mol O2 at 1000°C and 1500°C, what are the following values? Please draw lines on the accompanying Ellingham diagram (Figure 1) to clearly show your work. You may use more than one diagram (i.e., cut and paste this diagram).
a) ΔG for PbO
b) ΔG for UO2
c) CO/CO2 ratio
d) ΔH for CO
e) ΔH for H2O
f) CO/H2O ratio
1010 10-6 10-3 104 10
CO/CO2
1010-6 10-4 103 102 10
00
Ag2O
NiO
10-10
104
CuO
-250
PbO
H2O
FeO
102
10-6
CO2
103
10
CO
N2O
MnO
10-8
500
10
ZnO
10-10
10
10
10-12
Al2O3
106
10
ZrO2
-750
UO2
107
BeO
10
10-10
107
109
10-15
1000
10
10-20
107
Ni
10
100
10-22
102
1250
500
1000
CO/CO2
1
10
10-24
Temperature
H2/H2O
1013
10
PO2
10-9
0
105
1010
10-34
10-30
-23
Figure 1. Ellingham Diagram for selected metal/metal oxides. Basis is 1 mol O2.