2. Schrodinger equation
In quantum mechanics, physical quantities correspond to Hermitian operators. In particular, the total energy of the system corresponds to the Hamiltonian operator H, which is a hermitian operator. The ‘state of the system’ is a time dependent vector in an inner product space, |Έ(t)⌡. The state of the system obeys the Schrodinger equation
iħ d/dt |Έ(t)⌡ = H|Έ(t)⌡.
We assume that there are no time-varying external forces on the system, so that the Hamiltonian operator H is not itself time-dependent.
a) Take the Hermitian conjugate of the Schrodinger equation, which puts it into bra form (this is a simple one-liner; use the fact that H is hermitian).
b) Show that 〈Έ(t)|Έ(t)⌡ is time independent, i.e.
d/dt 〈Έ(t)|Έ(t)⌡ = 0.
(hint: use the product rule). This means that we can normalize the state vector at one time, say t = 0, so that 〈Έ(0)|Έ(0)⌡ = 1, and it will stay normalized at all times, 〈Έ(t)|Έ(t)⌡ = 1.
c) Define the time-evolution operator
U(t) = e^{-iHt/ħ}
where the exponential is defined by a Taylor expansion in powers of H:
U(t) = I - (it/ħ)H + 1/2 (-it/ħ)^2 H^2 + ...
Show that U(t) is unitary: U(t)† U(t) = U(t)U(t)† = I.
d) Let f(H) be any function of H that can be defined by a Taylor expansion in powers of H. Show that H and f(H) commute.
e) Find an expression for d/dt U(t).
f) Show that |Έ(t)⌡ = U(t)|Έ(0)⌡ is a solution of the Schrodinger equation. Here |Έ(0)⌡ is the initial state of the system, which we assume is given.