00:01
Hello students, in this question we have been given this equation where nitrogen in the gaseous state reacts with 3 molars of hydrogen in gaseous states and gives us 2 molars of ammonia in gaseous state.
00:19
Now here if we write the equilibrium constant, it will be given as partial pressure of n h 3 to the power 2 divided by partial pressure of n 2 to the power 1 because it is 1 into partial pressure of h2 to the power 3 and this equilibrium constant will be called as k p now we need to understand what is the relation between kp and k c how are they related now, if i have kc, which will be written as concentration of products divided by concentration of reactant.
01:18
Correct.
01:19
Now, we also know from the idle gas equation, pv is equal to n rt.
01:32
And if i rewrite this equation, it can be written as p is equal to n by v.
01:38
Into r t and this n by v is nothing but concentration so p is equal to c r t so if i put this value over here what i get is k p is equal to c of n h 3 and r t to the power to divided by concentration of n2 into r t to the power 1 because here it is 1 into concentration of h2 into r t to the power 3 because here's sociometric coefficient is 3 so kp is equal to concentration of n h 3 to the power 2 divided by concentration of n2 into concentration of h2 into r t to the power 2 and below it will be r t to the part 1 plus 3 okay now if i read this equation kp is equal to k c into r t 2 minus 4 3 plus 1 becomes 4 so i will write it over here as 4 so when it goes up it becomes minus.
03:20
So kp is equal to kc into rt to the power 2 minus 4.
03:26
Now this is whole.
03:29
This whole rt to the power 4 and this rt to the power 2.
03:33
So in the simplified form, we can write it as kp is equal to kc into rt read by rt to the power rt...