A 1.500 g pecan is burned in the experiment. It heats up a soda can filled with 200.0 mL of water (remember that the density of water is 1.00 g/mL) and raises the temperature of the water from 19.50 °C to 32.25 °C. The final mass of the pecan is found to be 0.850 g. What is the energy released per gram of the nut burned in kcal?