Antimony-bismuth is an alloy which finds applications in semiconductor and thermoelectric devices. The phase diagram for the antimony-bismuth system is shown below. A sample of composition 60 wt% Sb is made up and held at 400°C. Based on this information and the phase diagram below, answer the following questions: (i) What is the melting point of pure bismuth (Bi) and antimony (Sb)? (ii) What is the composition of any solid phase present? (iii) What is the composition of any liquid phase present? (iv) How much of each phase is present?
650-
600 550
Liquid (L)
400
300
Solid (a)
250
200 Bi
10 20
70 80 90 100 Composition (wt%Sb) Sb [17 marks]