A sample consisting of 1.00 mol of perfect gas molecules at 27 °C is expanded isothermally from an initial pressure of 3.00 atm to a final pressure of 1.00 atm in two ways: (a) reversibly, and (b) against a constant external pressure of 1.00 atm and Tsurr = 27 °C. Determine the values of q, w, ΔU, ΔH, ΔS, ΔSsurr, and ΔStot for each path.