00:01
All right so we have a question on solubility here.
00:03
It says a solution of contains fluoride salt of calcium and magnesium.
00:09
The concentration of calcium is 0 .07 molar 0 .070 molar.
00:20
Let's just write that again 0 .070 molar while the concentration of magnesium ion is 0 .050 molar.
00:36
Right okay so the first question says we should write the dissociation reactions in water for both compounds.
00:49
Obviously we're also given the ksp.
00:50
We're given the ksp of calcium fluoride that is given to us as 6 that's 3 .9 times 10 to the power of minus 11 while that of magnesium fluoride is much smaller magnesium fluoride we have that to be 6 .5 times 10 to the power of minus 9.
01:18
Okay it's much bigger sorry not smaller.
01:21
Okay so the first question it says we should write the equation.
01:24
So this is the equation for the dissociation of both salts.
01:28
You have magnesium fluoride and two moles of fluoride ion while for calcium fluoride you have two moles of fluoride plus calcium.
01:41
It doesn't matter the order you write it just switch the dot.
01:45
The next one says which solution will dissolve first.
01:53
The solution that will dissolve first is the one with a higher ksp value because the higher the ksp value the more soluble that salt is.
02:01
That's what it means.
02:02
So magnesium fluoride will dissolve first...