Assume you wish to determine the concentrations of Ca+ in an aqueous sample containing both Ca+ and Ni+ using an EDTA titration. This can be done by titrating two aliquots 1 and 2 each at different pH values: pH=4 and pH=8.
The experiment was done as follows:
[EDTA] = 0.06650 M
Volume of Aliquot 1 = 10.00 mL
pH of Aliquot 1 = 4
Equivalence volume for aliquot 1 (pH=4) = 4.49 mL
Volume of Aliquot 2 = 10.00 mL
pH of Aliquot 2 = 8
Equivalence volume for aliquot 2 (pH=8) = 15.80 mL
Calculate the concentration of Ca2+ in the sample. Report your answer to three (3) significant digits.