Below the mass spectrum, bromobenzene chlorobenzene
16. Why is there an unusually tall (M+2)+ peak and small (M+3)+ peak present? Bromobenzene isotope analysis shows that it contains 1 atom of carbon-13 (C13) and 1 atom of deuterium (D). The mass spectrum of bromobenzene (C6H5Br) shows the (M+2)+ peak at m/z 77 and the (M+3)+ peak at m/z 78.