Calculate the bond energy for the formation of boron trifluoride. Br—Br + 3 F—F ? 2 Br—F Average Bond Enthalpies (kJ/mol) Single Bonds C—H 413 N—H 391 O—H 463 F—F 155 C—C 348 N—N 163 O—O 146 C—N 293 N—O 201 O—F 190 Cl—F 253 C—O 358 N—F 272 O—Cl 203 Cl—Cl 242 C—F 485 N—Cl 200 O—I 234 C—Cl 328 N—Br 243 Br—F 237 C—Br 276 S—H 339 Br—Cl 218 C—I 240 H—H 436 S—F 327 Br—Br 193 C—S 259 H—F 567 S—Cl 253 H—Cl 431 S—Br 218 I—Cl 208 Si—H 323 H—Br 366 S—S 266 I—Br 175 Si—Si 226 H—I 299 I—I 151 Si—C 301 Si—O 368 Multiple Bonds C=C 614 N=N 418 O? 495 C?C 839 N?N 941 C=N 615 S=O 523 C?N 891 S=S 418 C=O 799 C?O 1072
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BF3 has one boron atom and three fluorine atoms, so it has three B-F single bonds. We need to find the bond energy for a single B-F bond. From the given data, we can see that the bond energy for a single B-F bond is 485 kJ/mol. Now, we need to calculate the Show more…
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Use the molar bond enthalpy data in the table to estimate the value of ΔH°rxn for the equation: CCl4(g) + 2 F2(g) → CF4(g) + 2 Cl2(g) The bonding in the molecules is shown. Average molar bond enthalpies. (Hbond) Bond | kJ · mol⁻¹ O–H | 464 O–O | 142 C–O | 351 O=O | 502 C=O | 730 C–C | 347 C=C | 615 C≡C | 811 C–H | 414 C–F | 439 C–Cl | 331 C–Br | 276 C–N | 293 C=N | 615 C≡N | 890 N–H | 390 N–N | 159 N=N | 418 N≡N | 945 F–F | 155 Cl–Cl | 243 Br–Br | 192 H–H | 435 H–F | 565 H–Cl | 431 H–Br | 368 H–S | 364 S–S | 225
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Use the molar bond enthalpy data in the table to estimate the value of ΔH°rxn for the equation CCl4(g) + 2F2(g) → CF4(g) + 2Cl2(g). The bonding in the molecules is shown.
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