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1. Calculate the concentration of a solution prepared by adding 15.00 mL of 2.09 x 10^-3 M KMnO4 from a buret into a 50.00 mL volumetric flask, which is then filled to the 50.00 mL graduation mark with distilled water. Hint: M 2. A linear standard curve of KMnO4 is prepared from a set of standard solutions by plotting absorbance (y) vs. concentration (x). Use Google Sheets/Excel to plot this standard curve using the data in Table 1. Help with spreadsheets [PDF] Table 1: Data for the standard curve of KMnO4 Absorbance Concentration (M) 0.342 6.00 x 10^-4 0.274 4.80 x 10^-4 0.205 3.60 x 10^-4 0.137 2.40 x 10^-4 0.0684 1.2 x 10^-4 After plotting the standard curve, enter its slope below (not the equation of the line). Report your answer to 3 significant figures. If your answer ends in one or more zeros, use scientific notation. Slope = M^-1 3. Suppose that an unknown sample is analyzed spectrophotometrically at the same wavelength that was used for the standard curve and the absorbance was found to be 0.200. Use the standard curve to find the concentration of the unknown. Hint: M Submit Question

          1. Calculate the concentration of a solution prepared by adding 15.00 mL of 2.09 x 10^-3 M KMnO4 from a buret into a 50.00 mL volumetric flask, which is then filled to the 50.00 mL graduation mark with distilled water. Hint:
M
2. A linear standard curve of KMnO4 is prepared from a set of standard solutions by plotting absorbance (y) vs. concentration (x). Use Google Sheets/Excel to plot this standard curve using the data in Table 1. Help with spreadsheets [PDF]
Table 1: Data for the standard curve of KMnO4
Absorbance Concentration (M)
0.342 6.00 x 10^-4
0.274 4.80 x 10^-4
0.205 3.60 x 10^-4
0.137 2.40 x 10^-4
0.0684 1.2 x 10^-4
After plotting the standard curve, enter its slope below (not the equation of the line). Report your answer to 3 significant figures. If your answer ends in one or more zeros, use scientific notation.
Slope = M^-1
3. Suppose that an unknown sample is analyzed spectrophotometrically at the same wavelength that was used for the standard curve and the absorbance was found to be 0.200. Use the standard curve to find the concentration of the unknown. Hint:
M
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1. Calculate the concentration of a solution prepared by adding 15.00 mL of 2.09 x 10^-3 M KMnO4 from a buret into a 50.00 mL volumetric flask, which is then filled to the 50.00 mL graduation mark with distilled water. Hint:
M
2. A linear standard curve of KMnO4 is prepared from a set of standard solutions by plotting absorbance (y) vs. concentration (x). Use Google Sheets/Excel to plot this standard curve using the data in Table 1. Help with spreadsheets [PDF]
Table 1: Data for the standard curve of KMnO4
Absorbance Concentration (M)
0.342 6.00 x 10^-4
0.274 4.80 x 10^-4
0.205 3.60 x 10^-4
0.137 2.40 x 10^-4
0.0684 1.2 x 10^-4
After plotting the standard curve, enter its slope below (not the equation of the line). Report your answer to 3 significant figures. If your answer ends in one or more zeros, use scientific notation.
Slope = M^-1
3. Suppose that an unknown sample is analyzed spectrophotometrically at the same wavelength that was used for the standard curve and the absorbance was found to be 0.200. Use the standard curve to find the concentration of the unknown. Hint:
M
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Chemistry: Structure and Properties
Chemistry: Structure and Properties
Nivaldo Tro 2nd Edition
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Calculate the concentration of a solution prepared by adding 15.00 mL of 2.09 x 10^-3 M KMnO4 from a buret into a 50.00 mL volumetric flask, which is then filled to the 50.00 mL graduation mark with distilled water. Hint: M 2. A linear standard curve of KMnO4 is prepared from a set of standard solutions by plotting absorbance (y) vs. concentration (x). Use Google Sheets/Excel to plot this standard curve using the data in Table 1. Table 1: Data for the standard curve of KMnO4 Absorbance Concentration (M) 0.342 6.00 x 10^-4 0.274 4.80 x 10^-4 0.205 3.60 x 10^-4 0.137 2.40 x 10^-4 0.0684 1.2 x 10^-4 After plotting the standard curve, enter its slope below (not the equation of the line). Report your answer to 3 significant figures. If your answer ends in one or more zeros, use scientific notation. Slope = M^-1 3. Suppose that an unknown sample is analyzed spectrophotometrically at the same wavelength that was used for the standard curve and the absorbance was found to be 0.200. Use the standard curve to find the concentration of the unknown. Hint: M Submit Question
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A. The absorbance of a cationic iron(II) sample solution was measured in a spectrophotometer, but the instrument returned an error because the absorbance was too high. The sample was then diluted by using a pipette to take 100.0 ÎĽL of the sample and injecting it into a cuvette already containing 2.00 mL of water (total volume is 2.00 mL + 100.0 ÎĽL). The absorbance value of the diluted solution corresponded to a concentration of 7.66Ă—10^-6 M. What was the concentration of the original solution? Give the molar concentration as a decimal number, do not use scientific notation. Round the number to the millionths of a molar. B. What volume of a 1.6 M stock solution do you need to prepare 500. mL of a 4.6 M solution of MgSO4? Write the answer rounded to the hundredths of a mL.

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Transcript

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00:01 To calculate the concentration of the prepared solution, we'll use the dilution equation.
00:06 The dilution equation is c1v1 equals c2 v2.
00:12 So the new concentration, c2, will be equal to the original concentration multiplied by the original volume divided by the new volume.
00:21 The original concentration was 2 .09 times 10 to the negative 3 molar.
00:28 We took 15 milliliters of that and we diluted it to a new volume of 50 milliliters and we get a new concentration of 6 .27 times 10 to the negative 4 molar kmno4.
00:57 The best way to answer the next question is to plot the data.
01:02 So if i go into excel and i plot the absorbent or the concentrate, the absorbance as a function of concentration, then i end up getting a graph that looks something like this.
01:20 And if i add the equation of the line, then i can see that the slope is to three significant figures, 570.
01:31 Now knowing the equation of the line, i can calculate the concentration from any absorbance value because y is absorbance and x is concentration.
01:43 I just plug in the absorbance and i solve for x the concentration...
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