Consider the conduction electrons in silver, which is monovalent (one free electron per atom), has a mass density 10.5 !! 10 kg m, and an atomic weight of 107. Show that the Fermi energy (at T = 0) is
ΙF = 5.6 eV,
and the equivalent temperature—the so-called Fermi temperature—is
TF = ΙF / k = 65,000 K.
Thus, if T ≪ TF (as is definitely the case at room temperature) then the conduction electrons are highly degenerate. Furthermore, show that at room temperature (T = 300 K), the contribution of the conduction electrons to the molar specific heat is only
cV(e) / R = 2.2 !! 10.