00:01
Hello students, so let's discuss part a of the question.
00:07
Under these conditions, will the pressure of n204 tend to rise or fall? so definitely pressure of n204 will fall.
00:23
Because initially n204 is n204 will start dissociating and since it is in equilibrium, so n -o -2 will be formed at that time.
00:37
So definitely its pressure will be going to decrease.
00:46
Now, because initially there were no reactants.
00:50
That's why pressure of the gas will fall initially.
00:56
Now, is it possible to reverse this tendency by adding n -o -2? now, yes, it is possible.
01:03
Yes, it is possible.
01:09
It is possible because if we no2 then definitely pressure will increase and it will its molecule will start associating and they will form n204.
01:23
So after that, in other words if you set the pressure of n2o4 will tend to rise, can be changed to a tendency to fall by adding no2.
01:35
Similarly, if you said the pressure of n2o4 will tend to fall, can be changed to a tendency to fall.
01:40
Can that be changed to a tendency to rise by adding no2? now answer to the question would be yes.
01:51
And let's prove that and also calculate the pressure.
01:56
Now since as we know, delta g note is equal to minus rt lnk, where delta g is the standard gives free energy or is the gas constant, is temperature and k is the equilibrium constant.
02:11
Now since we are given delta g note delta g note is equal to minus 5 .4 kilojoule...