Estimate the width of a spectral line in both frequency ($\nu$, Hz) and wavenumbers ($\tilde{\nu}$, cm$^{-1}$) originating from the decay of a state with a lifetime of 1 ns. (Note: $E = h\nu = \frac{hc}{\lambda} = hc\tilde{\nu}$)
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Step 1: The uncertainty principle states that the product of the uncertainty in energy (ΔE) and the uncertainty in time (Δt) is greater than or equal to Planck's constant divided by 4π: $$ΔEΔt ≥ \frac{h}{4π}$$ Show more…
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Assuming that the width of a spectral line solely depends on the natural line width, estimate the lifetime of a state that gives rise to a line with the width given below a. 2.6 cm⁻¹ b. 0.15 Hz
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