(i) Prove that \( \langle X \rangle \) remains unchanged under unitary transformation. (ii) The Hamiltonian operator \( H \) acting on a square integrable function \( \Psi(x, t) \) satisfies the Schrodinger equation \( ih \frac{\partial}{\partial t} \Psi(r, t) = H \Psi(r, t) \). Prove that for the probability conservation, the operator \( H \) must be Hermitian. (iii) Prove that the scalar product is invariant under unitary transformation.
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Step 1: The Schrödinger equation is given by: \[i\hbar \frac{\partial \Psi}{\partial t} = H \Psi\] where \(\Psi\) is the wave function, \(t\) is time, \(H\) is the Hamiltonian operator, and \(\hbar\) is the reduced Planck's constant. Show more…
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The general definition of a Hermitian operator, M† = M, implies that ✈f|M†|g✉ = ✈Mf|g✉ = ✈f|M|g✉ = ✈f|Mg✉. If |f✉ and |g✉ are continuous functions, then the integral representation of the Hermiticity condition is ∫[Mf(x)]* g(x) dx = ∫ f*(x) Mg(x) dx. a) By expanding the functions f and g in a complete, orthonormal basis, {|Δn✉}, derive equation (2) from the matrix-element definition of Hermiticity, Mij = M*ji, where Mij = ✈Δi|M|Δj✉. b) Prove that the momentum operator, p = -iħ d/dx, is Hermitian in the space of continuous, square-integrable functions of x ∈ (-∞, ∞). c) Is the operator D = d/dx Hermitian in this space? Prove your answer. d) Is the operator D^2 = d^2/dx^2 Hermitian in this space? Prove your answer.
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