00:01
So first we want to show that the wave functions are orthogonal.
00:05
And to do that, we need to show that the integral of si m star times si of m prime, dv is equal to the chronicler delta, which is equal to one when m is equal to m prime and zero when m is not equal to m prime.
00:30
And so m and m prime just refers to two different wave functions.
00:39
So note that r x square plus y squared plus z squared is a radial function that depends only on r.
00:49
So it is spherically symmetric.
00:50
It does not affect the angular part of the integration.
00:54
Thus, the orthogonality of it.
00:57
So let me say spherical symmetric.
01:05
So that means that the orthogonality of the way functions.
01:12
Will be determined by the angular integrals of x, y, and z in terms of the expressions of the wave functions.
01:35
So the integral plus 1 star, side 0 dv is equal to 0 because sii plus 1 has an x plus iy factor, while si not has a z factor...