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How will you distinguish between the following isomer pairs? (a) [CoBr(NH3)5]SO4 and [Co(SO4)(NH3)5]Br (b) [Cr(H2O)6]Cl3 and [CrCl(H2O)5]Cl2 H2O (c) Cis [PtCl2(NH3)2] and trans[PtCl2(NH3)2] (d) The two entiomers of [CoCl2(en)2]+

          How will you distinguish between the following isomer pairs? (a) [CoBr(NH3)5]SO4 and [Co(SO4)(NH3)5]Br (b) [Cr(H2O)6]Cl3 and [CrCl(H2O)5]Cl2 H2O (c) Cis [PtCl2(NH3)2] and trans[PtCl2(NH3)2] (d) The two entiomers of [CoCl2(en)2]+
        

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The Pearson Guide to Inorganic Chemistry for the IIT JEE and NEET
The Pearson Guide to Inorganic Chemistry for the IIT JEE and NEET
Atul Singhal 2012 Edition
Chapter 7
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How will you distinguish between the following isomer pairs? (a) [CoBr(NH3)5]SO4 and [Co(SO4)(NH3)5]Br (b) [Cr(H2O)6]Cl3 and [CrCl(H2O)5]Cl2 H2O (c) Cis [PtCl2(NH3)2] and trans[PtCl2(NH3)2] (d) The two entiomers of [CoCl2(en)2]+
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Which of these pair does not represent any type of constitutional isomerism here? (a) $\left[\mathrm{Co}\left(\mathrm{N} 1 \mathrm{I}_{3}\right), \mathrm{Br}\right] \mathrm{SO}_{1}$ and $\left[\mathrm{Co}\left(\mathrm{N} 1 \mathrm{l}_{3}\right)_{5} \mathrm{SO}_{1}\right] \mathrm{Br}$ (b) $\left[\mathrm{CrCl}\left(\mathrm{H}_{2} \mathrm{O}\right)_{3}\right] \mathrm{Cl}_{2} \cdot \mathrm{H}_{2} \mathrm{O}$ and $\left[\mathrm{CrCl}_{2}\left(\mathrm{H}_{2} \mathrm{O}\right)_{4}\right]$ $\mathrm{Cl}_{2} \mathrm{H}_{2} \mathrm{O}$ (c) $\mathrm{Cis}-\left[\mathrm{CrCl}_{2}(\mathrm{Ox})\right]^{3}$ and rrans-[CrCl $_{2}$ $\left.(\mathrm{Ox})_{2}\right]^{3}$ (d) $\left[\operatorname{Pr}\left(\mathrm{NII}_{3}\right)_{4}\right](\mathrm{PtCl})$ and $\left[\operatorname{Pr}\left(\mathrm{N} 1 \mathrm{I}_{3}\right)_{4} \mathrm{Cl}_{2}\right]$ $\left(\operatorname{PrCl}_{4}\right)$

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For any of the following that can exist as isomers, state the type of isomerism and draw the structures: (a) $\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{5} \mathrm{Cl}\right] \mathrm{Br}_{2}$ (b) $\left[\mathrm{Pt}\left(\mathrm{CH}_{3} \mathrm{NH}_{2}\right)_{3} \mathrm{Cl}\right] \mathrm{Br}$ (c) $\left[\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{4}\left(\mathrm{NH}_{3}\right)_{2}\right]^{2+}$

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Which one of the following is an example of coordination isomerism? A. [Co(NH3)5Br]SO4 and [Co(NH3)5SO4]Br B. [Co(NH3)5NO2]Cl2 and [Co(NH3)5ONO]Cl2 C. [Cr(H2O)6]Cl3 and [Cr(H2O)5Cl]Cl2· H2O D. [Cr(NH3)6][Co(CN)6] and [Co(NH3)6][Cr(CN)6]

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Transcript

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00:01 So we have to categorize the following isomr pairs.
00:03 Okay, they are the coordination complexes.
00:08 A part we have, so we have cobalt here.
00:12 Cobalt is the central atom, central metal.
00:16 Bromo group is here.
00:18 Amine group is here.
00:21 Five amine groups.
00:23 And we have s -o -4.
00:27 Okay.
00:30 So, and we have another.
00:34 Structure, cobalt is here, sulfate is here, and then we have amine group here five times, okay, and we have bromo group.
00:54 So i hope you have noticed then there is exchange of this bromo and sulfate lysant, okay? the cobalt is the central metal and these, other rest are the bromo group amine group sulfates so these are the liens okay now here we have exchange of license from the outside of coordination sphere to the inner side of coordination sphere right so when such exchange of license takes place okay so there is exchange of license of license in fact, an ion flight and they are hence called ionization isomal.
02:01 Then we have b part.
02:03 This time we have given crh2o whole 6 and we have we have, let me draw this again, cl3 and we have cr cl h2o whole 5 cl 2 h2 o .5 cl2 h2o okay so now here again we have a exchange of license actually right if you have noticed so there is exchange of chloro and this hydrate lysant right when you have hydrate line that especially okay so then we categorize this as hydration isomalism...
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