00:01
Determine the equilibrium pressure of the no nitrogen monoxide for this reaction and we are given this information.
00:12
We are given a kc but we are given pressures of gases so our starting pressures for all of these for all three gases is 0 .00176.
00:31
Okay so since we're given pressures for gases we can't use kc instead we need to use kp or find kp.
00:40
So kp equals kc times rt to the delta n.
00:44
R is our gas constant, t is our temperature.
00:47
We aren't given the temperature at all for this however delta n is our change in moles of gas from one side to the other.
00:56
So if we look at this reaction up here at the top we have one mole of n2, one mole of o2, and two moles of no.
01:04
So 2 minus 2 is 0 so in this case then delta n equals 0.
01:10
Anything to the 0 power equals 1 so that would mean that this also is the value for our kp.
01:18
Okay so that was the first battle.
01:20
So then the next battle is to figure out which way this reaction will shift since we have all three gases initially.
01:29
So we have to calculate q and we are going to compare k and q.
01:36
Let me fix this here.
01:37
We are going to calculate k and q.
01:41
So k is 0 .261.
01:46
Q is going to equal our products over our reactants raised to their powers.
01:53
So we would have concentration of no squared over the concentration of n2 to the first and o2 to the first.
02:03
Now that means it's going to be 0 .00176 squared over 0 .00176 squared which means q equals 1.
02:16
So then we can figure out which way this reaction will shift.
02:21
If you compare these if you always put them k before q alphabetical order like i have here then this arrow the greater than less than sign points the direction that gets the plus x's.
02:35
So our change for this is going to be plus x.
02:38
Our change for this will be plus x and our change for this will be minus 2x.
02:45
So if we write this in terms of plus x that's in terms of x 0 .00176 plus x and then here 0 .00176 whoops minus 2x.
03:04
Then we can set this up...