Question

2 Draw the organic products formed in each reaction. a. Br b. B Li$_2$CO$_3$, LiBr f. DMF [1] Br$_2$, CH$_3$CO$_2$H [2] Li$_2$CO$_3$, LiBr, DMF : COOH ? I$_2$ (excess) g. -OH COOH [1] LDA c. CH$_3$CH$_2$CH$_2$CO$_2$Et h. NaH [2] CH$_3$CH$_2$I CI CN C$_6$H$_9$N Br d. (CH$_3$)$_2$CHNH$_2$ i. [1] LDA ith Br$_2$ (excess) -OH NaI nucleophile e. [2] CH$_3$CH$_2$I j. CI

          2 Draw the organic products formed in each reaction.
a.
Br
b.
B
Li$_2$CO$_3$, LiBr
f.
DMF
[1] Br$_2$, CH$_3$CO$_2$H
[2] Li$_2$CO$_3$, LiBr, DMF
: 
COOH
?
I$_2$ (excess)
g.
-OH
COOH
[1] LDA
c. CH$_3$CH$_2$CH$_2$CO$_2$Et
h.
NaH
[2] CH$_3$CH$_2$I
CI
CN
C$_6$H$_9$N
Br
d.
(CH$_3$)$_2$CHNH$_2$
i.
[1] LDA
ith
Br$_2$ (excess)
-OH
NaI nucleophile
e.
[2] CH$_3$CH$_2$I
j.
CI

2 Draw the organic products formed in each reaction.
a.
Br
b.
B
Li2CO3, LiBr
f.
DMF
[1] Br2, CH3CO2H
[2] Li2CO3, LiBr, DMF
:
COOH
?
I2 (excess)
g.
-OH
COOH
[1] LDA
c. CH3CH2CH2CO2Et
h.
NaH
[2] CH3CH2I
CI
CN
C6H9N
Br
d.
(CH3)2CHNH2
i.
[1] LDA
ith
Br2 (excess)
-OH
NaI nucleophile
e.
[2] CH3CH2I
j.
CI

Added by Michael M.

Chemistry: Structure and Properties

Nivaldo Tro 2nd Edition

Instant Answer

Solved by Expert Raghvendra Singh

Step 1

It can result in the formation of a carboxylate salt and bromide ion. - The carboxylate salt can be written as LiOOC-COOLi. - The bromide ion can be written as Br⁻. Show more…

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Please help with these reactions! Draw the organic products formed in each reaction. LiCOâ‚ƒ + LiBr + DMF a [1] Brâ‚‚, CHâ‚ƒCOH [2] LiCOâ‚ƒ, LiBr, DMF Br COOH Iâ‚‚ (excess) HOâ» COOH c. CHâ‚ƒCHCHCOEt [1] LDA [2] CHâ‚‚CHI NaH CN Câ‚†Hâ‚…N (CHâ‚ƒ)â‚‚CHNHâ‚‚ Br (excess) -OH nucleophile NaI Cl [1] LDA [2] CHâ‚‚CHI