Q # 4. The gas-phase reaction between butadiene and ethylene to form cyclohexene can be written as follows:
C4H6 + C2H4 → C6H10
Feed consisting of equimolar amounts of each reactant enters a tubular flow reactor at 1 atm and at 450°C. Determine the space time needed to convert 10% of the feed for (i) isothermal, and (ii) adiabatic operation. Write equations describing the exact solution for each case. Use estimates where appropriate.
Data:
k = 107.5 exp (-27,500/RT) L/mol-sec
Hr = -30,000 cal/mol
Cp = 36.8 cal/mol-°C
C°s = 20.2 cal/mol-°C
Cpc = 59.5 cal/mol-°C