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Table 5.1 Chemical formulas and acidity constants at 25°C of some important acids(a) Name Formula pKa1 pKa2 pKa3 pKa4 Hydrochloric acid HCl < 0 Sulfuric acid H2SO4 < 0 1.99 Hydronium ion H3O+ 0.00 14.00 Chromic acid H2CrO4 0.20 6.51 Oxalic acid (COOH)2 1.250 4.266 Sulfurous acid H2SO3 1.85 7.19 Ferric ion Fe3+ 2.02 3.73 9.25 7.70 Phosphoric acid H3PO4 2.148 7.198 12.375 Arsenic acid H3AsO4 2.20 7.01 11.80 Salicylic acid C6H4OHCOOH 2.972 13.7 Citric acid C3H4OH(COOH)3 3.128 4.761 6.396 Hydrofluoric acid HF 3.18 Benzoic acid C6H5COOH 4.20 Pentachlorophenol acid C6Cl5OH 4.7 Acetic acid CH3COOH 4.757 Propionic acid CH3CH2COOH 4.874 Carbonic acid H2CO3 6.352 10.329 Hydrogen sulfide H2S 7.02 17.4 Cupric ion Cu2+ 7.497 8.73 10.41 13.09

          Table 5.1 Chemical formulas and acidity constants at 25°C of some important acids(a)

Name Formula pKa1 pKa2 pKa3 pKa4
Hydrochloric acid HCl < 0
Sulfuric acid H2SO4 < 0 1.99
Hydronium ion H3O+ 0.00 14.00
Chromic acid H2CrO4 0.20 6.51
Oxalic acid (COOH)2 1.250 4.266
Sulfurous acid H2SO3 1.85 7.19
Ferric ion Fe3+ 2.02 3.73 9.25 7.70
Phosphoric acid H3PO4 2.148 7.198 12.375
Arsenic acid H3AsO4 2.20 7.01 11.80
Salicylic acid C6H4OHCOOH 2.972 13.7
Citric acid C3H4OH(COOH)3 3.128 4.761 6.396
Hydrofluoric acid HF 3.18
Benzoic acid C6H5COOH 4.20
Pentachlorophenol acid C6Cl5OH 4.7
Acetic acid CH3COOH 4.757
Propionic acid CH3CH2COOH 4.874
Carbonic acid H2CO3 6.352 10.329
Hydrogen sulfide H2S 7.02 17.4
Cupric ion Cu2+ 7.497 8.73 10.41 13.09
        
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Table 5.1 Chemical formulas and acidity constants at 25°C of some important acids(a)

Name Formula pKa1 pKa2 pKa3 pKa4
Hydrochloric acid HCl < 0
Sulfuric acid H2SO4 < 0 1.99
Hydronium ion H3O+ 0.00 14.00
Chromic acid H2CrO4 0.20 6.51
Oxalic acid (COOH)2 1.250 4.266
Sulfurous acid H2SO3 1.85 7.19
Ferric ion Fe3+ 2.02 3.73 9.25 7.70
Phosphoric acid H3PO4 2.148 7.198 12.375
Arsenic acid H3AsO4 2.20 7.01 11.80
Salicylic acid C6H4OHCOOH 2.972 13.7
Citric acid C3H4OH(COOH)3 3.128 4.761 6.396
Hydrofluoric acid HF 3.18
Benzoic acid C6H5COOH 4.20
Pentachlorophenol acid C6Cl5OH 4.7
Acetic acid CH3COOH 4.757
Propionic acid CH3CH2COOH 4.874
Carbonic acid H2CO3 6.352 10.329
Hydrogen sulfide H2S 7.02 17.4
Cupric ion Cu2+ 7.497 8.73 10.41 13.09

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Chemistry: Structure and Properties
Chemistry: Structure and Properties
Nivaldo Tro 2nd Edition
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Table 5.1 Chemical formulas and acidity constants at 25°C of some important acids Name Formula pKa1 pKa2 pKa3 pKa4 Hydrochloric acid HCl < 0 Sulfuric acid H2SO4 < 0 1.99 Hydronium ion H3O+ 0.00 14.00 Chromic acid H2CrO4 0.20 6.51 Oxalic acid (COOH)2 1.250 4.266 Sulfurous acid H2SO3 1.85 7.19 Ferric ion Fe3+ 2.02 3.73 9.25 7.70 Phosphoric acid H3PO4 2.148 7.198 12.375 Arsenic acid H3AsO4 2.20 7.01 11.80 Salicylic acid C6H4OHCOOH 2.972 13.7 Citric acid C3H4OH(COOH)3 3.128 4.761 6.396 Hydrofluoric acid HF 3.18 Benzoic acid C6H5COOH 4.20 Pentachlorophenol acid C6Cl5OH 4.7 Acetic acid CH3COOH 4.757 Propionic acid CH3CH2COOH 4.874 Carbonic acid H2CO3 6.352 10.329 Hydrogen sulfide H2S 7.02 17.4 Cupric ion Cu2+ 7.497 8.73 10.41 13.09
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Suman K.

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Use the table below to find all the acids that are stronger than acetic acid and weaker than formic acid. Ka and pKa Values for Weak Monoprotic Acids at 25 °C Name of Acid | Formula | Ka | pKa Iodic acid | HIO3 | 1.7 × 10^-1 | 0.77 Chloroacetic acid | HC2H2O2Cl | 1.4 × 10^-3 | 2.85 Nitrous acid | HNO2 | 4.6 × 10^-4 | 3.34 Hydrofluoric acid | HF | 3.5 × 10^-4 | 3.46 Cyanic acid | HOCN | 2 × 10^-4 | 3.7 Formic acid | HCHO2 | 1.8 × 10^-4 | 3.74 Barbituric acid | HC4H3N2O3 | 9.8 × 10^-5 | 4.01 Hydrazoic acid | HN3 | 2.5 × 10^-5 | 4.60 Acetic acid | HC2H3O2 | 1.8 × 10^-5 | 4.74 Butanoic acid | HC4H7O2 | 1.5 × 10^-5 | 4.82 Propanoic acid | HC3H5O2 | 1.3 × 10^-5 | 4.89 Hypochlorous acid | HOCl | 3.0 × 10^-8 | 7.52 Hydrocyanic acid | HCN | 4.9 × 10^-10 | 9.31

David C.

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Calculate the pH if 10.0 mL of 0.020 M benzoic acid is added to 40.0 mL of 0.004 M sodium benzoate. The pKa of benzoic acid is 4.20. HA + H2O ⇌ H3O+ + A- benzoic acid benzoate anion Conj. acid/base pair Initial moles of benzoic acid, "HA" = CHA · VHA = (0.020M)(0.010L) = 2.0x10-4 moles Initial moles of benzoate anion, "A-" = CA- · VA- = (0.004M)(0.040L) = 1.6x10-4 moles Assuming there won't be much dissociation of the weak acid or protonation of the conjugate base, we can use the Henderson-Hasselbalch equation here. (There won't be much change because benzoic acid is a weak acid and we are mixing it with its conjugate base, so this assumption is ok) pH = pKa + log([A-] / [HA]) benzoate anion benzoic acid MUST be a conj. acid/base pair! ALWAYS when using H-H. pH = 4.20 + log(1.6x10-4 moles / VTOT / 2.0x10-4 moles / VTOT) pH = 4.20 + log(0.8) = 4.20 + (-0.0969) pH = 4.10 Is this a buffer? YES VTOT (total volume) terms cancel -> you CAN use moles in H-H (but NEVER in Ka eqn)

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00:01 Hey everyone, the solution of this question is the dipeptide, dipeptide ala cys is the combination of two amino acids.
00:13 This is the combination of two amino acid...
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