The concentration of a solution of EDTA was determined by standardizing against a solution of Ca2+ prepared from the primary standard CaCO3. A 0.4071-g sample of CaCO3 was transferred to a 500-mL volumetric flask, dissolved using a minimum of 6 M HCl, and diluted to volume. A 50.00-mL portion of this solution was transferred into a 250-mL Erlenmeyer flask and the pH adjusted by adding 5 mL of a pH 10 NH3–NH4Cl buffer containing a small amount of Mg2+–EDTA. After adding calmagite as a visual indicator, the solution was titrated with the EDTA, requiring 42.63 mL to reach the end point. Report the molar concentration of the titrant.