The enthalpy change, ΔH, is the quantity of heat transferred into or out of a system as it undergoes a chemical or a physical change at constant pressure. In short: ΔH is heat change at constant pressure. Note that there really isn't much new here. We've already discussed heat a lot during our thermodynamic discussions. Since heat is not a state function, it turns out that the amount of heat absorbed or released as a system undergoes a change is dependent on how that change occurs - the pathway of the change. This means that if a reaction occurs at constant pressure it might have a different value for q than if it occurred while pressure was changing. Since we often carry out reactions at constant pressure - picture an open beaker on a lab bench - we give q at constant pressure a special name, enthalpy. If you see the term enthalpy or its symbol, H, you know it means "heat at constant pressure". We can symbolize this as qp, where the subscript p indicates "constant pressure". ΔH = qp
The process of water condensing at 100 °C is
- Endothermic with ΔH > 0 and w > 0
- Endothermic with ΔH > 0 and w < 0
- Endothermic with ΔH < 0 and w < 0
- Exothermic with ΔH < 0 and w < 0
- Exothermic with ΔH < 0 and w > 0
- Exothermic with ΔH > 0 and w > 0