The stepwise formation constants for complexes of $mathrm{NH}_{3}$ with $left[mathrm{Cu}left(mathrm{OH}_{2}
ight)_{6}
ight]^{2+}(mathrm{aq})$ are $log K_{mathrm{n}}=4.15, log K_{mathrm{e}}=3.50, log K_{mathrm{B}}=2.89$ $log K_{4}=2.13,$ and $log K_{1 s}=-0.52 .$ Suggest a reason why $K_{i s}$ is so different.