Find out the Effective Atomic Number, hybridization, magnetic moment in the following compounds. (i) [V(CO)6] (ii) [Fe(CO)5]
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Write the hybridization and magnetic character of the following complexes: (i) [Fe(H2O)6]2+ (ii) [Ni(CN)4]2- [Atomic number: Fe = 26, Ni = 28]
Sri K.
1. Determine which of the following is paramagnetic, estimate its magnetic moment. [Fe(CN)6]4-, [Co(H2O)6]3+, [CoF6]3-, [RhF6]3- 2. What are the possible magnetic moments of Co(II) in tetrahedral, octahedral and square-planar complexes? 3. Stepwise stability constants in aqueous solution at 25°C for the formation of the iron for copper and nickel are given. Why is there such a difference in the third values? [M(en)(H2O)4]2+ [M(en)2(H2O)2]2+ [M(en)3]2+ Cu 3x10^10 1x10^9 0.1 Ni 2x10^7 1x10^6 1x10^4 4. a. Find the number of unpaired electrons, magnetic moment, ligand field stabilization energy for the following Cu(CN)6]4-, [Cu(H2O)6]2+, [Co(CO)4]-, MnO4-, [Co(NO2)6]4- b. Why is the tetrahedral geometry more stable for Co(II) than for Ni(II)? 5. Consider the trigonal bipyramidal and square pyramidal structures and predict which one is more suitable for Ni(II). 6. Comment on whether the following coordination complexes possess the Jan-Teller distortion. [CrI6]4-, [Cr(CN)6]4-, [CoF6]3-, [Mn(ox)3]3- 7. For which member is Δ_oct larger? [Cr(OH2)6]3+ or [Cr(OH2)6]2+ [CrF6]3- or [Cr(NH3)6]3+ [MnF6]2- or [ReF6]2- [Co(en)3]3+ or [Rh(en)3]3+"
Adi S.
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