Question

A 12CH335Cl molecule has a C-Cl bond length of 178 pm, a C-H bond length of 111 pm, and an HCH angle of 110.5°. Identify whether the molecule is oblate or prolate, and calculate its rotational energy terms.

          A 12CH335Cl molecule has a C-Cl bond length of 178 pm, a C-H bond length of 111 pm, and an HCH angle of 110.5°. Identify whether the molecule is oblate or prolate, and calculate its rotational energy terms.
        

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Chemistry: Structure and Properties
Chemistry: Structure and Properties
Nivaldo Tro 2nd Edition
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A 12CH335Cl molecule has a C-Cl bond length of 178 pm, a C-H bond length of 111 pm, and an HCH angle of 110.5°. Identify whether the molecule is oblate or prolate, and calculate its rotational energy terms.
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Transcript

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00:01 Del e is equal to b j dash plus 1 minus b of j now where this j dash and j are the rotational quantum numbers of the upper and lower states and b is the rotational constant now for the transition from j is equal to 2 to j is equal to 3 in c power 120 power 16 we have del e is equal to b of 3 minus b of 2 it is equal to 2 centimeter inverse to determine the bond length of this we will use the expression for the rotational constant which is b is equal to h by 8 pi square cl now where this h is planck's constant this c is the speed of light and this l…
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