00:01
Okay, so we have given here a chemical reaction.
00:03
Let me first write that this is 4x plus 3y gives p and now rate.
00:11
So by rate law, okay, we are writing the rate by rate law or rate equation.
00:20
So rate is equals to k multiplied by concentration of x multiplied by concentration of y so the concentration of reactants are to be considered here okay so now for trial one so now we have rate is equals to k multiplied by zero 0 .020 multiplied by 0 .060 okay now here it is to be keep in mind that the powers are also here so these power raised to power m and raised to power n so these are actually the order with respect to each concentration okay these orders are determined experimentally okay so now that's why here we can write raise to power m and raise to power n respectively also this rate value so that is also given to us so let me put that so this is 3 .40 multiplying 10 raised to power minus 3 okay so now consider this as first equation similarly now for trial 2 so now the rate is 2 .72 2 multiplying 10 raised to power minus 2 okay and that is equals to k multiplied by concentration of the reactant 0 .020 raised to power m 0 .120 raised to power n okay consider this as second equation okay now by 1 divided by 2 so this will be 3 .40 multiplying 10 raised to power minus 3 divided by 2 .72 multiplying 10 and raised to power minus 2.
03:35
And now k to k will be cancelled out 0 .020 molar sorry raised to power m.
03:44
And this will also be cancelled out.
03:46
Okay.
03:46
So let me write it again.
03:49
So this will be like 0 .020 divided by 0 .020 raised to power m.
03:56
We can consider the power as whole.
03:59
Right.
04:00
And this will be 0 .060 divided by 0 .120 raised to power n okay now solving this so this will be 1 .25 multiplying 10 raised to power minus 1 is equals to now solving this this will be 1 and now solving this this will be this is 0 .5 raised to power n okay now i can write this 1 .25 as shifting the decimal this can also be written as simply this is we have 0 .125 okay now this can also be further can also be written as 0 .5 raised to power 3 okay so if 0 .5 is multiplied three times we will get 0 .125 right and that is equals to 0 .5 raised to power n now when the base value is same so now the exponent values are equal to each other so now this can be written as or n is equals to 3 ok so that is the value for n now for trial 3 so we have information that 1 .36 6 multiplying 10 raised to power minus 2 that is equals to 0 .8 a multiplied by 0 .0 8 0 raised to power m multiplied by 0 .0 6 0 raised to power n okay consider this has third equation okay so this is the third equation let me write it again now by 3 divided by 1 now we can write that 0 point or let me write it again so this this is 1 .36 multiplying 10 raised to power minus 2 divided by 3 .40 multiplying 10 raised to power minus 3...