Which of the following is a statement of the 2nd law of thermodynamics: All spontaneous reactions cause an decrease in the entropy of the system. A completely ordered, pure crystalline solid at zero K has an entropy of zero. All spontaneous changes cause an increase in the entropy of the universe. Energy can be transformed from one form to another, but cannot be created nor destroyed. The change in Free Energy (ΔG) of a spontaneous reaction must be positive.