Question

You added 2.5 g of solid Ba(OH)2 in 50.0 mL of pure water at 25 degrees C. Some of the solid was dissolved and the pH of the solution was found to be 13.32. Estimate the value of Ksp for Ba(OH)2.

          You added 2.5 g of solid Ba(OH)2 in 50.0 mL of pure water at 25 degrees C. Some of the solid was dissolved and the pH of the solution was found to be 13.32. Estimate the value of Ksp for Ba(OH)2.
        

Added by Ines M.

Chemistry: Structure and Properties
Chemistry: Structure and Properties
Nivaldo Tro 2nd Edition
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You added 2.5 g of solid Ba(OH)2 in 50.0 mL of pure water at 25 degrees C. Some of the solid was dissolved and the pH of the solution was found to be 13.32. Estimate the value of Ksp for Ba(OH)2.
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Transcript

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00:01 To calculate ksp, we first need to know the ksp expression.
00:05 The ksp expression comes from solid, barium hydroxide, dissociating to produce barium ion and two hydroxides.
00:18 So, ksp, which excludes solids, will simply be equal to the barium concentration, multiplied by the hydroxide concentration squared.
00:30 So, at equilibrium, they've given us, the barium concentration and the ph.
00:36 The ph can be used to calculate the hydroxide concentration.
00:40 The barium concentration is 0 .138 molar.
00:47 The hydroxide concentration is equal to kw, 1 .0 times 10 to the minus 14, divided by the hydronium concentration...
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