You are given an electrochemical cell where the chemical reaction involves a silver complex. A silver metal bar is used as the positive electrode. The electrochemical potential for this cell is given by:
E = EºAg+/Ag - 0.0592 (volts) * log(1/[Ag+])
For a test solution with a silver concentration of 0.001 M, the electrochemical cell potential is 0.20 volts. Find the silver electrode potential EºAg+/Ag.
This same cell from (a) is used to measure the electrochemical potential for a new silver complex in equilibrium. If the measured cell potential is 0.324 volts, what is the silver concentration for this new silver complex at equilibrium?