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Problems and Solutions in Organic Chemistry for JEE MAIN AND ADVANCED

Surendra K. Mishra

Chapter 9

Biomolecules, Practical Organic Chemistry (POC) and Polymers - all with Video Answers

Educators


Section 1

JEE (Main) Exercises

01:01

Problem 1

Amino acid having no chiral centre is
(A) Valine
(B) Alanine
(C) Glycine
(D)Proline

Narayan Hari
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01:01

Problem 2

Camphor and napthalene can be purified by1
(A) Recrystallisation
(B) Fractional distillation
(C) Filtration
(D) Sublimation

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02:37

Problem 3

The pollutants which come directly in the air from sources are called primary pollutants. Primary pollutants are
sometimes converted into secondary pollutants. Which of the following belongs to secondary air pollutants?
(A) $\mathrm{CO}$
(B) Hydrocarbon
(C) Peroxyacetyl nitrate
(D) $\mathrm{NO}$

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01:02

Problem 4

$p K_{a}$ values for Alanine is $2.3$ and 9.7. Alanine would exist as a cation at pH equal to
(A) $2.3$
(B) 6
(C) $9.7$
(D) 12

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01:01

Problem 5

Isoelectric point of Alanine is 6 . At which pH maximum concentration of zwitter ion of alanine will be present?
(A) $\mathrm{pH}>6$
(B) $\mathrm{pH}<6$
(C) $\mathrm{pH}=6$
(D) $\mathrm{pH}=7$

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01:01

Problem 6

Mixture of anthracene and benzoic acid can be separated by
(A) Fractional distillation
(B) Sublimation
(C) Chromatography
(D) Filtration

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01:01

Problem 7

Among the following, which is not a synthetic polymer?
(A) Polythene
(B) Buna-S
(C) Cellulose
(D) Nylon-6,6

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01:01

Problem 8

Structure of glycine at $\mathrm{pH}=10.5$ is
(A)
(B)
(C)
(D) $\mathrm{CH}_{2}-\mathrm{COO}^{-}$ $\mathrm{NH}_{2}$

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03:16

Problem 9

Glycine and Alanine can form how many sequence (primary structure) of Tripepetides?
(A) 2
(B) 6
(C) 8
(D) 4

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01:01

Problem 10

Isoelectric point of Aspartic acid is
(A) 2
(B) 5
(C) 3
(D) $6.5$

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01:47

Problem 11

The compound is/are
(A) Aldohexose
(B) Furanose
(C) Pyranose
(D) Both (A) and (C)

Raghvendra Singh
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01:01

Problem 12

Glycerol is added to soap because it functions as
(A) Afiller
(B) To increase lathering
(C) To prevent rapid drying
(D) To make soap granules

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01:01

Problem 13

In solution, glucose exists in how many isomeric forms?
(A) Two
(B) Sixteen
(C) Three
(D) Four

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01:01

Problem 14

The most stable isomers of glucose is
(A) Aldehydic form
(B) $\alpha$-form
(C) Keto form
(D) $\beta$-form

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01:01

Problem 15

The principle involved in paper chromatography is
(A) Adsorption
(B) Partition
(C) Solubility
(D) Volatility

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02:41

Problem 16

Photochemical smog occurs in warm, dry and sunny climate. One of the following is not amongst the components
of photochemical smog, identify it.
(A) $\mathrm{NO}_{2}$
(B) $\mathrm{O}_{3}$
(C) $\mathrm{SO}_{2}$
(D) Unsaturated hydrocarbon

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01:01

Problem 17

The acid not present in acid rain is
(A) Peroxyacetylnitrate
(B) $\mathrm{H}_{2} \mathrm{CO}_{3}$
(C) $\mathrm{HNO}_{3}$
(D) $\mathrm{H}_{2} \mathrm{SO}_{4}$

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03:52

Problem 18

Specific rotation of equilibrium mixture of the three forms of glucose is
(A) $52.2^{\circ}$
(B) $112^{\circ}$
(C) $19.5^{\circ}$
(D) $-90^{\circ}$

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01:01

Problem 19

Which of the following polymers of glucose is stored by animals?
(A) Cellulose
(B) Amylose
(C) Amylopectin
(D) Glycogen

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01:01

Problem 20

Which is a non-reducing sugar?
(A) Lactose
(B) Cellulose
(C) Maltose
(D) Sucrose

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01:01

Problem 21

Glucose reacts with acetic anhydride to form
(A) Mono acetate
(B) Tetra acetate
(C) Penta acetate
(D) Hexa acetate

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01:04

Problem 22

Which of the following is not a semisynthetic polymer?
(A) cis-polyisoprene
(B) Cellulose nitrate
(C) Cellulose acetate
(D) Vulcanised rubber

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01:01

Problem 23

In the given reaction, value of $n$ is
Glucose $+$ n Phenylhydrazine $\longrightarrow$ Osazone
(A) Three
(B) Two
(C) One
(D) Four

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01:07

Problem 24

The consequences of global warming may be
(A) Increase in average temperature of the earth
(B) Melting of Himalayan Glaciers
(C) Increased biochemical oxygen demand
(D) All of these

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01:02

Problem 25

At which carbon the following sugars are epimers of each other?
(A) $\mathrm{C}-1$
(B) $\mathrm{C}-2$
(C) $\mathrm{C}-3$
(D) $\mathrm{C}-4$

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01:04

Problem 26

The incorrect statement is
(A) Galactose and glucose are epimers
(B) Glucose and mannose are anomers
(C) Glucose and fructose both can show mutarotation
(D) $\alpha$-D-Glucopyranose and $\beta$-D-Glucopyranose both are stereoisomers

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01:01

Problem 27

Invert sugar is (
A) Sucrose
(B) Fructose
(C) Glucose
(D) Equimolar mixture of glucose and fructose

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01:02

Problem 28

Which one of the following carbohydrates will show mutarotation?
(A) Sucrose
(B) Starch
(C) Cellulose
(D)Maltose

Narayan Hari
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01:01

Problem 29

Select the biodegradable polymer.
(A) Buna-S
(C) PHBV
(B) Nylon-2-Nylon-6
(D) Both (B) and (C)

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03:02

Problem 30

Number of chiral centre in pyranose form of glucose is
(A) 4
(B) 6
(C) 5
(D) 3

Anand Jangid
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01:01

Problem 31

Butyne-1 and butyne-2 can be distinguished by
(A) $\mathrm{Br}_{2} / \mathrm{H}_{2} \mathrm{O}$
(B) $\mathrm{NaOH}$
(C) $\mathrm{Cu}_{2} \mathrm{Cl}_{2} / \mathrm{NH}_{4} \mathrm{OH}$
(D) $\mathrm{H}_{2}-\mathrm{Pt}$

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01:04

Problem 32

The commercial name of polyacrylonitrile is
(A) Dacron
(B) Orlon (acrolin)
(C) $\mathrm{PVC}$
(D) Bakelite

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Numerade Educator
01:04

Problem 33

The commercial name of polyacrylonitrile is
(A) Dacron
(B) Orlon (acrolin)
(C) $\mathrm{PVC}$
(D) Bakelite

Narayan Hari
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01:01

Problem 34

Prussian blue obtained in detection of nitrogen is
(A) $\mathrm{Na}_{4}\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]$
(B) $\mathrm{Fe}_{4}\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]_{3}$
(C) $\mathrm{Na}_{4}\left[\mathrm{Fe}(\mathrm{CN})_{5} \mathrm{NOS}\right]$
(D) $\mathrm{Na}_{2}[\mathrm{Fe}(\mathrm{SCN})]$

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01:37

Problem 35

Positive Tollen's test is not shown by

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01:01

Problem 36

Yellow crystal of $\mathrm{CHI}_{3}$ is obtained using iodoform test by
(A) $\mathrm{CH}_{3}-\mathrm{CH}_{2} \mathrm{OH}$
(B) $\mathrm{CH}_{3}-\mathrm{CH}=\mathrm{O}$
(C) $\mathrm{CH}_{3}-\mathrm{C}-\mathrm{CH}_{2}-\mathrm{C}-\mathrm{CH}_{3}$
(D) All of these

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01:01

Problem 37

During determination of degree of alcohol by Victor Mayer test, red colour is obtained by
(A) $3^{\circ}$ alcohol
(B) $1^{\circ}$ alcohol
(C) $2^{\circ}$ alcohol
(D) All of these

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01:02

Problem 38

The compounds which on treatment with dilute HNO $_{3}$ never gives ethyne as a product.
(A) $\mathrm{CaC}_{2}$
(B) $\mathrm{Ag}_{2} \mathrm{C}_{2}$
(C) $\mathrm{Cu}_{2} \mathrm{C}_{2}$
(D) $\mathrm{Be}_{2} \mathrm{C}$

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01:01

Problem 39

Which compound never show positive iodoform test?
(A) Lactic acid
(B) Acetophenone
(C) Benzophenone
(D) Pyruvic acid

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01:12

Problem 40

Monomer of nylon-66 is

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01:01

Problem 41

Choose the correct option.
(A) Invertase involves
Decomposition of urea into $\mathrm{NH}_{3}$ and $\mathrm{CO}_{2}$
(B) Maltase involves Hydrolysis of cane sugar
(C) Urease involves Hydrolysis of maltose into glucose
(D) Zymase involves Conversion of glucose into ethyl alcohol

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02:41

Problem 42

The Hinsberg test of a compound, $\mathrm{C}_{5} \mathrm{H}_{14} \mathrm{~N}_{2}$ produces a solid that is insoluble in $10 \%$ aq. $\mathrm{NaOH}$. This solid derivative dissolves in $10 \%$ aqueous sulphuric acid. Which of the following would best describe these facts?
(A) $\mathrm{NH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{~N}\left(\mathrm{CH}_{3}\right)_{2}$
(B) $\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NCH}_{2} \mathrm{CH}_{2} \mathrm{NHCH}_{3}$
(C) $\mathrm{NH}_{2} \mathrm{CH}_{2} \mathrm{C}\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CH}_{2} \mathrm{NH}_{2}$
(D) $\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NCH}_{2} \mathrm{~N}\left(\mathrm{CH}_{3}\right)_{2}$

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01:44

Problem 43

Which of the following statements is not true about classical smog?
(A) Its main components are produced by the action of sunlight on emissions of automobiles.
(B) Produced in cold and humid climate
(C) It contains compounds of reducing nature
(D) It contains smoke, fog and sulphur dioxide

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01:01

Problem 44

Which of the following are used as antacids?
(A) Aluminium and magnesium hydroxide
(C) Metal hydroxides
(B) $\mathrm{NaHCO}_{3}$
(D) All of these

Narayan Hari
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01:01

Problem 45

Which of the following is/are belongs to non-narcotic analgesic?
(A) Morphine
(B) Aspirin
(C) Paracetamol
(D) Both (B) and (C)

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01:30

Problem 46

Biochemical Oxygen Demand, (BOD) is a measure of organic material present in water. BOD value less than 5 ppm indicates a water sample to be
(A) rich in dissolved oxygen
(B) poor in dissolved oxygen
(C) highly polluted
(D) not suitable for aquatic life

Anand Jangid
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01:02

Problem 47

Which of the following does not belong to broad spectrum antibiotics?
(A) Penicilin G
(B)Ampicilin
(C) Amoxycillin
(D) Chloramphenicol

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01:01

Problem 48

Bithionol is added to soaps to impart properties of
(A) Antipyretic
(B) Antibiotic
(C) Analgesic
(D) Antiseptic

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01:01

Problem 49

Which of the following statements is wrong?
(A) Ozone is not responsible for green house effect.
(B) Ozone can oxidise sulphur dioxide present in the atmosphere to sulphur trioxide.
(C) Ozone hole is thinning of ozone layer present in stratosphere.
(D) Ozone is produced in upper stratosphere by the action of UV rays on oxygen.

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01:01

Problem 50

DNA and RNA contain four bases each. Which of the following bases is not present in RNA?
(A) Adenine
(B) Uracil
(C) Thymine
(D) Cytosine

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01:01

Problem 51

Which of the following is used for weak antiseptic for eyes?
(A) Iodoform
(B) Tincture of iodine
(C) Boric acid in dil. solution
(D) Bithional

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01:01

Problem 52

Which of the following is not disinfectant?
(A) $0.2 \%$ of phenol
(C) Chlorine in $0.2$ to $0.4 \mathrm{ppm}$
(B) $\mathrm{SO}_{2}$ in very low concentration
(D) $1 \%$ of phenol

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01:01

Problem 53

Dettol is made of
(A) Furacine
(B) Chloroxylenol
(C) Terpineol
(D) Both (B) and (C)

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01:01

Problem 54

Choose the incorrect option.
(A) Iodoform is used as antispetic
(B) 2 - $3 \%$ of iodine in alcohol water is known as tincture of iodine
(C) Furacine is used as antispetic
(D) Terpineol contains one chlorine

Narayan Hari
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Numerade Educator
01:01

Problem 55

Which of the following statements is not true about low density polythene?
(A) Tough
(B) Hard
(C) Poor conductor of electricity
(D) Highly branched structure

Narayan Hari
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Numerade Educator
03:09

Problem 56

Which of the following antihistamine does not affect secretion of acid?
(A) Cimetidine
(B) Ranitidine
(C) Terfenadine
(D) Histamine

Anand Jangid
Anand Jangid
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02:03

Problem 57

Which of the following is not in class of tranquilizer called barbiturates?
(A) Veronal
(B) Amytal
(C) Equanil
(D) Luminal

Anand Jangid
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01:55

Problem 58

Which of the following has highest and lowest value of sweetness respectively?
(A) Aspartame, Alitame
(B) Saccharin, Sucrolose
(C) Alitame, Aspartame
(D) Sucrolose, Alitame

Anand Jangid
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01:04

Problem 59

Which of the following artificial sweetner contains chlorine?
(A) Aspartame
(B) Sucrolose
(C) Saccharin
(D) Alitame

Narayan Hari
Narayan Hari
Numerade Educator
01:01

Problem 60

Which of the following gases is not a green house gas?
(A) $\mathrm{CO}$
(B) $\mathrm{O}_{3}$
(C) $\mathrm{CH}_{4}$
(D) $\mathrm{H}_{2} \mathrm{O}$ vapour

Narayan Hari
Narayan Hari
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