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Heat and Thermodynamics

M. W. Zemansky, Richard H. Dittman

Chapter 11

Open Systems - all with Video Answers

Educators


Chapter Questions

04:30

Problem 1

(a) Show that in a Joule-Thomson expansion, no temperature change occurs if $(\partial \nu / \partial T)_{P}=v / T$
(b) Show that
$$
\mu c_{P}=T\left(\frac{\partial \nu}{\partial T}\right)_{P}-\nu .
$$
In the region of moderate pressures, the equation of state of $1 \mathrm{~mol}$ of gas may be written
$$
P v=R T+B^{\prime} P+C^{\prime} P^{2}
$$
where the second and third virial coefficients $B^{\prime}$ and $C^{\prime}$ are functions of $T$ only.
(c) Show that, as the pressure approaches zero,
$$
\mu c_{P} \rightarrow T \frac{d B^{\prime}}{d T}-B^{\prime}
$$
(d) Show that the equation of the inversion curve is
$$
P=-\frac{B^{\prime}-T\left(d B^{\prime} / d T\right)}{C^{\prime}-T\left(d C^{\prime} / d T\right)}
$$

Mahnoor Amin
Mahnoor Amin
Numerade Educator
02:15

Problem 2

The Joule-Thomson coefficient $\mu$ is a measure of the temperature change during a throttling process. A similar measure of the temperature change produced by an isentropic change of pressure is provided by the coefficient $\mu_{s}$, where
$$
\mu_{S}=\left(\frac{\partial T}{\partial P}\right)_{s}
$$
Prove that
$$
\mu_{S}-\mu=\frac{V}{C_{P}}
$$

Sheh Lit Chang
Sheh Lit Chang
University of Washington
09:55

Problem 3

According to Hill and Lounasmaa, the equation of the ${ }^{4} \mathrm{He}$ inversion curve is
$$
P=-21.0+5.44 T-0.132 T^{2}
$$
where $P$ is given in atmospheres.
(a) What is the maximum inversion temperature?
(b) What point on the inversion curve has the maximum pressure?

Megan Mcfarland
Megan Mcfarland
Numerade Educator
01:22

Problem 4

Derive the Clausius-Clapeyron equation from the third Maxwell's relation, namely,
$$
(\partial P / \partial T)_{V}=(\partial S / \partial V)_{T}
$$

Sheh Lit Chang
Sheh Lit Chang
University of Washington
03:46

Problem 5

Show that a substance with a negative slope for its fusion curve, such as ordinary ice or bismuth, contracts upon melting.

Ronald Prasad
Ronald Prasad
Numerade Educator
01:42

Problem 6

Saturated liquid carbon dioxide at a temperature of $293 \mathrm{~K}$ and a pressure of $5.72 \times 10^{6} \mathrm{~Pa}$ experiences throttling to a pressure of $1.01 \times 10^{5} \mathrm{~Pa}$. The temperature of the resulting mixture of solid and vapor is $195 \mathrm{~K}$. What fraction is vaporized? (The enthalpy of saturated liquid at the initial state is $24,200 \mathrm{~J} / \mathrm{mol}$, and the enthalpy of saturated solid at the final state is $6750 \mathrm{~J} / \mathrm{mol}$. The heat of sublimation at the final state is $25,100 \mathrm{~J} / \mathrm{mol}$.)

Narayan Hari
Narayan Hari
Numerade Educator
02:27

Problem 7

The latent heat of fusion for ice $I$ is $3.34 \times 10^{5} \mathrm{~J} / \mathrm{kg}$ at $0^{\circ} \mathrm{C}$ and atmospheric pressure. If the change in specific volume on melting is $-9.05 \times 10^{-5} \mathrm{~m}^{3} / \mathrm{kg}$, then calculate the change of melting temperature due to change of pressure.

Surendra Kumar
Surendra Kumar
Numerade Educator
01:22

Problem 8

Prove that, during a first-order phase transition:
(a) The entropy of the entire system is a linear function of the total volume.
(b) The change of internal energy is given by
$$
\Delta U=\Delta H\left(1-\frac{d \ln T}{d \ln P}\right)
$$

Ajay Singhal
Ajay Singhal
Numerade Educator
01:55

Problem 9

When lead is melted at atmospheric pressure, the melting point is $600 \mathrm{~K}$, the density decreases from $11.01$ to $10.65 \mathrm{~g} / \mathrm{cm}^{3}$, and the latent heat of fusion $\Delta H$ is $24.5 \mathrm{~J} / \mathrm{g}$. What is the melting point at the pressure of $1.01 \times 10^{7} \mathrm{~Pa}$ ?

Morgan Cheatham
Morgan Cheatham
Numerade Educator
05:19

Problem 10

Water at its freezing point $\left(T_{i}, P_{i}\right)$ completely fills a strong steel container. The temperature is reduced to $T_{f}$ at constant volume, with the pressure rising to $P_{f}$.
(a) Show that the fraction $y$ of water that freezes is given by
$$
y=\frac{v_{f}^{\prime \prime}-v_{f}^{n}}{v_{f}^{\prime \prime}-v_{f}^{\prime}}
$$
(b) State explicitly the simplifying assumptions that must be made in order that $y$ may be written
$$
y=\frac{v^{\prime \prime}\left[\beta^{\prime \prime}\left(T_{f}-T_{i}\right)-\kappa^{\prime \prime}\left(P_{f}-P_{i}\right)\right]}{v_{f}^{\theta}-v_{f}^{\prime}}
$$
(c) Calculate $y$ for $i=0^{\circ} \mathrm{C}, \quad 1.01 \times 10^{5} \mathrm{~Pa} ; \quad f=-5^{\circ} \mathrm{C}, \quad 5.98 \times 10^{7} \mathrm{~Pa}$;
$\beta^{\prime \prime}=-67 \times 10^{-6} \mathrm{~K}^{-1} ; \kappa^{\prime \prime}=12.04 \times 10^{-11} \mathrm{~Pa}^{-1} ; v_{f}^{\prime \prime}-v_{f}^{\prime}=-1.02 \times 10^{-4} \mathrm{~m}^{3} / \mathrm{kg}$

Ren Jie Tuieng
Ren Jie Tuieng
Numerade Educator
06:23

Problem 11

(a) Prove that, for a single phase,
$$
\left(\frac{\partial P}{\partial T}\right)_{S}=\frac{c_{P}}{T u \beta}
$$
(b) Calculate $(\partial P / \partial T)_{S}$ for ice at $-3^{\circ} \mathrm{C}$, where $c_{P}=2.01 \mathrm{~kJ} / \mathrm{kg} \cdot \mathrm{K}, v=1.09 \times$
$10^{-3} \mathrm{~m}^{3} / \mathrm{kg}$, and $\beta=1.58 \times 10^{-4} \mathrm{~K}^{-1}$
(c) Ice is initially at $-3^{\circ} \mathrm{C}$ and $1.01 \times 10^{5} \mathrm{~Pa}$. The pressure is increased adiabatically until the ice reaches the melting point. At what temperature and pressure is this melting point? (Hint: At what point does a line whose slope is $(\partial P / \partial T)_{S}$ cut a line whose slope is that of the fusion curve, $\left.-1.35 \times 10^{7} \mathrm{~Pa} / \mathrm{K} ?\right)$

Sheh Lit Chang
Sheh Lit Chang
University of Washington
05:28

Problem 12

Figure P11-1 shows the surface for the equation of state of water as viewed from the high-temperature end. Consider $1 \mathrm{~kg}$ of ice in the state $i\left(P_{i}=1.01 \times 10^{5} \mathrm{~Pa}\right.$ $\left.T_{i}=273 \mathrm{~K}\right)$
The ice experiences an isentropic compression to a state $f$ :
(a) Why is the state $f$ in the mixture region? In other words, why does some of the ice melt?
(b) Show that the fraction $x$ of ice that is melted is given by
$$
x=\frac{s_{f}^{\prime}-s_{i}^{\prime}}{s_{f}^{\prime \prime}-s_{f}^{\prime}}
$$
(c) State explicitly the simplifying assumptions that must be made in order that $x$ may be written
$$
x=-\frac{c_{P}^{\prime}\left(T_{f}-T_{i}\right)-T_{f} v^{\prime} \beta^{\prime}\left(P_{f}-P_{i}\right)}{\Delta h_{F}}
$$
(d) Calculate $x$ when $T_{f}=272 \mathrm{~K}, P_{f}=1.35 \times 10^{7} \mathrm{~Pa}, c_{P}^{\prime}=2.01 \mathrm{~kJ} / \mathrm{kg} \cdot \mathrm{K}, v^{\prime}=$
$1.09 \times 10^{-3} \mathrm{~m}^{3} / \mathrm{kg}, \beta^{\prime}=1.58 \times 10^{-4} \mathrm{~K}^{-1}$, and $\Delta h_{F}=334 \mathrm{~kJ} / \mathrm{kg}$.

Khoobchandra Agrawal
Khoobchandra Agrawal
Numerade Educator
07:17

Problem 13

A steel bar in the form of a rectangular parallelepiped of height $a$, breadth $b$, and length $c$ is embedded in a cake of ice as shown in Fig. PII-2. With the aid of an external magnetic field, a constant force $F$ is exerted downward on the bar. The whole system is at $0^{\circ} \mathrm{C}$.
(a) Show that the decrease in temperature of the ice directly below the bar is
$$
\Delta T=\frac{F T\left(v^{t}-v^{\prime \prime}\right)}{b c \Delta h_{F}}
$$
(b) Ice melts (see Prob. $11.12$ ) under the bar, and all the water thus formed is forced to the top of the bar, where it refreezes. This phenomenon is known as regelation. Heat, therefore, is liberated above the bar, is conducted through the metal and a layer of water under the metal, and is absorbed by the ice under
the layer of water. Show that the speed with which the bar sinks through the ice is
$$
\frac{d y}{d t}=\frac{U^{\prime} T\left(v^{\prime}-v^{\prime \prime}\right) F}{\rho\left(\Delta h_{F}\right)^{2} b c}
$$
where $U^{\prime}$ is the overall heat-transfer coefficient of the composite heat-conducting path consisting of the metal and the water layer. $U^{\prime}$ is given by
$$
\frac{1}{U^{\prime}}=\frac{x_{m}}{K_{m}}+\frac{x_{w}}{K_{w}}
$$
where $x_{m}$ and $x_{w}$ are the thicknesses of the metal and water layer, respectively, and $K_{m}$ and $K_{w}$ are their respective thermal conductivities.
(c) Assuming that the water layer has a thickness of about $10^{-5} \mathrm{~m}$ and a thermal conductivity of about $0.6 \mathrm{~W} / \mathrm{m} \cdot \mathrm{K}$, and that the bar is $0.1 \mathrm{~m}$ long, with $a$ and $b$ each equal to $10^{-3} \mathrm{~m}$, with what speed will the bar descend when $F=10^{2} \mathrm{~N} ?$ (Thermal conductivity of stecl is $60 \mathrm{~W} / \mathrm{m} \cdot \mathrm{K} .$ )

Carlos Henrique De Lima
Carlos Henrique De Lima
Numerade Educator
01:45

Problem 14

(a) From Eq. (11.22) derive the relation
$$
\left(\frac{\partial S}{\partial P}\right)_{H_{N}}=-\frac{V}{T}
$$
(b) For the ideal gas, the entropy as a function of $H, P, n$ has the form
$$
S(H, P, n)=R \ln \frac{f(H, n)}{P^{n}}
$$
where $f(H, n)$ is a function of the enthalpy $H$ and the number of moles $n$. Using the result from part ( $a$ ), derive the ideal-gas equation of state. (From $\mathrm{H} . \mathrm{W}$. Graben and J. R. Ray, Physical Review, Ser. A, vol. 43, pp. $4100-4103,1991 .$ )

James Kiss
James Kiss
Numerade Educator