Calculate the freezing point of each of the following solutions:
a. $1.36 \mathrm{~mol}$ of methanol, $\mathrm{CH}_{4} \mathrm{O}$, a nonelectrolyte, added to $1.00 \mathrm{~kg}$ of water
b. 640 . $\mathrm{g}$ of the antifreeze propylene glycol, $\mathrm{C}_{3} \mathrm{H}_{8} \mathrm{O}_{2}$, a nonelectrolyte, dissolved in $1.00 \mathrm{~kg}$ of water
c. $111 \mathrm{~g}$ of $\mathrm{KCl}$, a strong electrolyte, dissolved in $1.00 \mathrm{~kg}$ of water