Consider the matrix $A$ in $\mathrm{SU}(3)$ given by
$$
A=\left(\begin{array}{lll}
0 & 0 & 1 \\
1 & 0 & 0 \\
0 & 1 & 0
\end{array}\right)
$$
which maps $e_1$ to $e_2, e_2$ to $e_3$, and $e_3$ to $e_1$. Let $H$ be an arbitrary element of $\mathfrak{b}$ and let $\lambda_2, \lambda_2$, and $\lambda_3$ be the diagonal entries of $H$ (which must sum to zero). Compute by hand $A H A^{-1}$ and verify that this is related to $H$ as described in Section 5.6, namely that $\lambda_1$ gets shifted into the second spot, $\lambda_2$ gets shifted into the third spot, and $\lambda_3$ gets shifted into the first spot.