• Home
  • Textbooks
  • Competitive Physics: Thermodynamics, Electromagnetism and Relativity
  • Thermodynamics and Ideal Gases

Competitive Physics: Thermodynamics, Electromagnetism and Relativity

Wang Jinhui

Chapter 2

Thermodynamics and Ideal Gases - all with Video Answers

Educators


Chapter Questions

01:47

Problem 1

A constant volume gas thermometer is constructed from connecting a gas chamber of a fixed volume to a manometer. The difference $\Delta h$ in liquid levels in the manometer reflects the pressure of the gas in the chamber and the temperature $T$ of the gas can then be read off a pre-calibrated linear graph between $\Delta h$ and $T$. To measure the temperature of a substance (usually a liquid), the gas chamber is immersed in the substance such that its temperature becomes the temperature of the substance (the heat capacity of the gas is negligible). Now, a certain constant volume gas thermometer contains one mole of a gas whose equation of state is
$$
\left(p+\frac{a}{V^2}\right)(V-b)=R T
$$
where $a$ and $b$ are characteristic constants of the gas. This is known as the van der Waals equation of state and is commonly used to model real gases. Another constant volume gas thermometer contains one mole of an ideal gas which obeys the ideal gas law, $p V=R T$. The thermometers are calibrated at the ice and steam points to give centigrade scales. Show that the two thermometers will give identical readings when placed in thermal contact with a substance of any temperature.

Aadit Sharma
Aadit Sharma
Numerade Educator
05:51

Problem 2

Two thermally insulated vessels of volumes $V_1$ and $V_2$ initially contain monoatomic gases of initial pressures and temperatures $p_1, T_1$ and $p_2, T_2$. They are then linked by a thermally insulated tube. Determine the final pressure $p$ and temperature $T$.

Emily Anderson
Emily Anderson
Numerade Educator
01:58

Problem 2

Through the kinetic theory of gases, show that a process involving a monoatomic ideal gas in a thermally insulated container with a slowly moving and thermally insulated piston conserves the quantity $T V^{\frac{2}{3}}$ where $T$ and $V$ are the instantaneous temperature and volume respectively. The speed of the piston is very small as compared to the speed of the gas molecules. Assume that the collisions between the gas molecules and the piston are perfectly elastic.

Dheeraj Sharma
Dheeraj Sharma
Numerade Educator
01:14

Problem 3

A certain amount of helium is cooled at constant pressure $p_0$. As a result, its volume decreases from $V_0$ to $\frac{V_0}{2}$. Find the amount of heat lost in this process.

Khoobchandra Agrawal
Khoobchandra Agrawal
Numerade Educator
01:51

Problem 4

A helium balloon is allowed to rise to a height such that the external pressure is half of the ground pressure $p_1$. Its initial volume and temperature are $V_1$ and $T_1$ respectively. Assume that the envelope of the balloon is a perfect insulator and that the process is quasistatic. Calculate the final volume and temperature of the gas and the amount of work done by the gas. (Singapore Physics Olympiad)

Naman Kumar
Naman Kumar
Numerade Educator
01:10

Problem 5

The current pressure and volume of an ideal gas are $p_0$ and $V_0$. It then undergoes a cyclic process as follows. It first expands under the constraint that $p=p_0 V$ to $\left(2 p_0, 2 V_0\right)$. Then, its pressure is reduced isochorically from $2 p_0$ to $p_0$. Finally, it contracts isobarically until its volume returns to $V_0$. Determine the heat absorbed during this cyclic process.

Prem Bijarniya
Prem Bijarniya
Numerade Educator
22:38

Problem 6

A thermally insulated container of cross sectional area $A$ is separated into two compartments, A and B, by a frictionless divider which is a perfect insulator. Certain moles of an ideal gas with an adiabatic constant $\gamma$ fill the two compartments. A massless, thermally insulated piston at one end of compartment $\mathrm{B}$ is initially maintained at some pressure $p$. Initially, the system is at equilibrium such that volumes of $\mathrm{A}$ and $\mathrm{B}$ are $\frac{2}{3} A l$ and $\frac{1}{3} A l$. The pressure on the piston is then increased so gradually that the system is always at equilibrium, until the combined volume of the two compartments becomes $A l^{\prime}$. If the temperature increments in the two compartments are $\Delta T_A$ and $\Delta T_B$ respectively, determine the number of moles of ideal gas they contain, $n_A$ and $n_B$.

Brandy Heflin
Brandy Heflin
Numerade Educator
11:58

Problem 7

A gas-tight, thermally isolated cylinder of total volume $V$ is divided into two compartments $\mathrm{A}$ and $\mathrm{B}$ by a piston made of a conducting material, which can be controlled by an external agent outside the cylinder. Initially, $\mathrm{A}$ and $\mathrm{B}$ are of equal volume; they contain respectively 1 and 2 moles of an ideal monoatomic gas, all at temperature $T_0$ (the external agent holds the piston in place). The external agent then moves the piston to a position such that A and B possess final volumes $\frac{V}{3}$ and $\frac{2 V}{3}$ respectively. This is done sufficiently slowly for the temperatures of the two gas samples to remain uniform and equal throughout the process. Find an expression for the final temperature of the system while neglecting the heat capacity of the cylinder and piston.

Eric Mockensturm
Eric Mockensturm
Numerade Educator
03:09

Problem 8

A balloon with surface tension $\gamma$ (be wary that this is not the adiabatic index) is placed in a vacuum chamber and connected via a small tube to a gas container with a piston. The total number of moles of gas in the balloon and piston is $n$. The system is allowed to equilibrate such that the pressure of the gas in the combined system is $p_0$. If the system is maintained at a constant temperature $T$ and the pressure on the piston is quasistatically varied - such that the system is always at thermodynamic equilibrium - until all gas molecules in the piston are transferred to the balloon, determine the amount of work done on the gas by the piston. The final pressure of the gas is $p_1$. Assume that the balloon constantly maintains a spherical shape.
(GRAPH CAN'T COPY)

Abid Hussain
Abid Hussain
Numerade Educator
04:39

Problem 9

A container is partially filled with an ideal gas (on top) and incompressible water of density $\rho$. The initial pressure of the gas is $2 p_a$ where $p_a$ is the atmospheric pressure. If the small hole of area $A$ of the bottom of the container is opened such that water begins to flow out of the container, determine the time required for the water to stop flowing if the ideal gas undergoes an isothermal process such that $n R T=k$ where $k$ is a constant. Assume that the flow of water is energy conserving and steady and neglect any difference in pressure due to the height of the water. The velocity of water inside the container is also negligible. Assume that the temperature of the water remains constant as well.

Surendra Kumar
Surendra Kumar
Numerade Educator
22:38

Problem 10

A thermally insulated container with a movable, massless piston is connected to a thermally insulated tyre of constant volume $V$ via a thermally insulated tube. During each pumping cycle, the valve in the tube is first closed. Then, the piston is expanded until the pressure and volume of the gas becomes $p_a$ and $V_a$, by taking in air from the outside. The gas in the piston, which has an adiabatic index $\gamma$, is then compressed adiabatically until its volume becomes $\frac{V_0}{2}$. Finally, the valve is opened until equilibrium is reached between the container and the tyre. If the tyre does not contain any gas initially,determine the minimum number of cycles required to increase the pressure in the tyre to $2^{\gamma-1} p_a$.
(GRAPH CAN'T COPY)

Brandy Heflin
Brandy Heflin
Numerade Educator
05:27

Problem 11

An open container, exposed to the atmosphere, contains water of density $\rho_w$. An "L-shaped" tube is inserted into it as shown in the figure below. The diameter of the vertical part of the tube is negligible while the horizontal part of the tube has a uniform cross sectional area and length $l$. Initially, the tube is motionless such that the water level is completely flat at equilibrium. Subsequently, the tube is rotated at a constant angular velocity $\omega$ about the vertical column such that the water level in the tube is a height $\Delta h$ above the water level in the container at equilibrium. If the atmospheric pressure and temperature are $p_a$ and $T$ and if the molar mass of the gas inside the tube is $\mu$, determine $\Delta h$. Assume that the gas in the tube undergoes an isothermal process and $l^2 \omega^2 \ll \frac{R T}{\mu}$ where $R$ is the ideal gas constant.
(GRAPH CAN'T COPY)

Kudakwashe Mapiki
Kudakwashe Mapiki
Numerade Educator
06:20

Problem 12

A small cork of cross sectional area $A$ and mass $m$ blocks the opening of a wine bottle that is filled with an ideal gas with an adiabatic constant $\gamma$. If the atmospheric pressure is $p_0$ and the volume of gas inside the bottle is $V_0$ at the equilibrium state, determine the angular frequency of small oscillations of the cork about its equilibrium position.
(GRAPH CAN'T COPY)

Linda Winkler
Linda Winkler
Numerade Educator
03:20

Problem 13

A thermally insulated container with a constant cross sectional area $A$ is separated into an upper and lower compartment by a divider of mass $M$. The two compartments are filled with certain moles of ideal gas which can exchange heat with one another as the divider is not thermally insulated. A small ball of a certain mass $m$ is stuck to the bottom face of the divider. Initially, the ratio of the volumes of the upper and lower compartments is $3: 1$ and the pressure of the gas in the upper compartment is $p_1$. Then, the ball of mass $m$ falls from the divider and bounces on the bottom of the container, until it eventually comes to rest at the bottom of the lower compartment. If the final ratio of the volumes of the upper and lower compartments is $2: 1$, determine $m$.

Saman Zulfiqar
Saman Zulfiqar
Numerade Educator
03:17

Problem 14

An inverted container with a constant cross sectional area and mass $m$ is floating with its base at the water level as shown in the figure below. The height of the air column is $h_0$. The plate holding back the water on top is then removed such that water falls down at negligible velocity - causing the instantaneous depth of the container, which is defined to be the distance between the water level and the base of the container, to become $h_1$. The column of air between the two water sections dissolves and has no impact on the system. Argue qualitatively that the container should sink. If the entire set-up has a constant temperature $T$ and the gas in the container instantaneously attains thermodynamic equilibrium at every depth of the container, determine the velocity of the container at depth $h$ (assume that $\frac{h_0}{h}$ is small). Neglect atmospheric pressure. Now, interpret your results for $h_0 \rightarrow 0$.
(GRAPH CAN'T COPY)

Aman Gupta
Aman Gupta
Numerade Educator
03:20

Problem 15

Two tubes carrying an identical ideal gas flowing at pressures $p_1, p_2$ and temperatures $T_1, T_2$ merge at a junction into a combined third tube. If the flow velocities at all parts of the tubes are negligible and if the volume flow rate in the first tube is $k$ times that of the second tube, determine the temperature $T_3$ of the gas exiting from the third tube. The flow is and the tubes are thermally insulated.

Saman Zulfiqar
Saman Zulfiqar
Numerade Educator
04:17

Problem 16

A fan of cross sectional area $A$ steadily takes in diatomic air molecules of molar mass $\mu$, pressure $p_1$ and temperature $T_1$ and expels it at velocity $v_2$, pressure $p_2$ and temperature $T_2$. Determine the electric power needed to sustain the fan (assuming that it is perfectly efficient).

Mayukh Banik
Mayukh Banik
Numerade Educator
02:52

Problem 17

This problem will explore an elegant way of deriving the speed of a onedimensional sound wave in a gaseous medium: $c=\sqrt{\frac{\gamma p}{\rho}}$ where $\gamma, p$ and $\rho$ are the adiabatic index, ambient pressure and density of the gaseous medium. Suppose that the sound wave travels adiabatically in the $\mathrm{x}$-direction at velocity $c$ and that the currently oscillating point along the medium travels at a small velocity $-v(v \ll c)$ in the lab frame. The density of the currently oscillating section only differs from the ambient pressure by a small amount $\Delta \rho \ll \rho$. Think of a way to apply the equations describing steady flow (mass and energy continuity). Through these two equations and the adiabatic condition, you will obtain two equations that are linear combinations of two variables (one of which is $v$ ) that are equated to zero. By exploiting the fact that the determinant must be zero for the two variables to have non-trivial solutions, determine $c$.

Manish Jain
Manish Jain
Numerade Educator
01:23

Problem 18

Prove Eq. (2.39) by considering molecules traveling at a particular z-component of velocity $v_z$. You will have to relate $\left\langle v_z^2\right\rangle$ to $\left\langle v^2\right\rangle$. (Note that we did not use this simple proof in order to expedite the derivation of Eq. (2.40).)

Raj Bala
Raj Bala
Numerade Educator
01:20

Problem 19

Suppose that the energy of a system in a particular state, quantified by the variable $x$ which can range from $-\infty$ to $\infty$, is $E=\alpha x^2$ where $\alpha$ is a constant. If the probability of the system adopting a certain state follows the Boltzmann distribution, show that the average energy of the system is $\frac{1}{2} k T$, where $k$ is the Boltzmann constant and $T$ is the temperature of the system. If the energy of the system in a particular state is now $E=$ $\sum_{i=1}^N \alpha_i x_i^2$, where the $x_i^{\prime} s$ are independent variables that collectively define a state and each ranges from $-\infty$ to $\infty$, show that the average energy is given by $\frac{N}{2} k T$.

Dominador Tan
Dominador Tan
Numerade Educator
01:08

Problem 20

A container is separated into two compartments of volumes $V_1$ and $V_2$ by a massive divider. The first compartment initially contains $n_0$ moles of an ideal gas while the other compartment is empty. If a hole, with a diameter smaller than the mean free path of molecules, is made on the divider and the two compartments are maintained at temperatures $T_1$ and $T_2$, determine the pressure in each compartment when the system has equilibrated.

Narayan Hari
Narayan Hari
Numerade Educator
06:20

Problem 21

A hole of area $A$, whose diameter is smaller than the mean free path of gas molecules, is punctured on the surface of a container of volume $V$ that rests in a vacuum. If the initial number density of ideal gas molecules inside the container is $\eta_0$ and the gas is constantly in a state of equilibrium, determine the number density $\eta(t)$ if the gas is maintained at a constant temperature $T$ and if each molecule has mass $m$. Then, determine the external power supplied to the gas inside the cylinder. Neglect all form of energy loss, other than that due to the escaping molecules.

Linda Winkler
Linda Winkler
Numerade Educator
02:02

Problem 22

This problem concerns estimating the thermal conductivity of an ideal gas via the kinetic theory of gases. By Fourier's law of conduction, the heat flux density, or the power delivered per unit perpendicular area, across an area is proportional to the temperature gradient.
$$
\frac{d q}{d t}=-k \frac{d T}{d z}
$$
where the z-direction has been set as the direction along which temperature varies. $q$ is the heat flow per unit area - implying that $\frac{d q}{d t}$ is the power per unit area. The negative sign in the above equation implies that heat flows from regions of higher temperature to regions of lower temperature. Finally, $k$ is the thermal conductivity which we aim to determine in this problem.
Now, consider the following set-up. Two large plates parallel to the xy-plane are located at certain z-coordinates. They are maintained at different temperatures such that a steady, position-dependent temperature $T(z)$, that is strictly decreasing with increasing $z$, is set up in the region between them. An ideal gas with $f$ degrees of freedom fills this region.
(a) Argue qualitatively why there will be power delivered across a plane of a constant $z$-coordinate based on the varying temperature $T(z)$.
(b) It is known that the gas molecules have a mean free path $\lambda$. Now, consider a class of gas molecules with a certain velocity that makes an angle $\theta$ with the z-direction. If the gas molecules cut across a plane of z-coordinate $z$ at a particular instance, what is the average kinetic energy carried by them?
(c) Using the previous result, determine the heat flux density and thermal conductivity $k$ across a plane of z-coordinate $z$, in terms of the degrees of freedom of the gas molecules $f$, the number density $\eta$ (assumed to be uniform throughout), $\lambda$ and the average speed $\langle v\rangle$ of the gas molecules at a plane of z-coordinate $z$. Assume that $\lambda$ is small such that second order and above terms in $\lambda$ are negligible.

Stanley Enemuo
Stanley Enemuo
Numerade Educator
03:51

Problem 24

A hole of area $A$, whose diameter is smaller than the mean free path of gas molecules, is made on a thermally insulated container of volume $V$, that is placed in a large vacuum. If the initial number density of gas molecules inside the container is $\eta_0$ and the initial temperature is $T_0$, show that the number density $\eta(t)$ obeys
$$
\eta(t)=\frac{1}{\left(\eta_0^{-\frac{1}{6}}+A \sqrt{\frac{k T_0}{72 \pi m V^2 \eta_0^{\frac{1}{3}}}}\right)^6}
$$
where $m$ is the mass of one molecule. Assume that the gas inside the container constantly attains a homogeneous equilibrium state. Hint: consider the rate of change of number density and the internal energy of the gas inside the container.

Khoobchandra Agrawal
Khoobchandra Agrawal
Numerade Educator