Book cover for Chemistry Principles and Reactions

Chemistry Principles and Reactions

William L. Masterton, Cecile N. Hurley

ISBN #9781305079373

8th Edition

1,898 Questions

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46,084 Students Helped

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Summary

Chemistry Principles and Reactions is a comprehensive textbook that guides readers through the fundamental concepts of chemistry, starting with matter, measurements, and atomic theory and progressing to advanced topics such as thermodynamics, kinetics, and complex equilibria. The book is structured as a logical journey, building on precise measurements and elemental understanding to embed the critical principles behind chemical reactions, from stoichiometry and gas laws to acid–base behavior and organic synthesis. Throughout the text, clear explanations of concepts like molecular geometry, electron configurations, and reaction spontaneity are woven together with practical applications in electrochemistry, nuclear reactions, and materials chemistry. This cohesive framework not only reinforces the theoretical foundations of chemistry but also equips students with the quantitative tools and practical insights essential for mastering the subject.

Chapters & Topics Covered

Chapter 1

Matter and Measurements

Chapter 2

Atoms, Molecules, and lons

Chapter 3

Mass Relations in Chemistry; Stoichiometry

Chapter 4

Reactions in Aqueous Solution

Chapter 5

Gases

Chapter 6

Electronic Structure and the Periodic Table

Chapter 7

Covalent Bonding

Chapter 8

Thermochemistry

Chapter 9

Liquids and Solids

Chapter 10

Solutions

Chapter 11

Rate of Reaction

Chapter 12

Gaseous Chemical Equilibrium

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Chapter 13

Acids and Bases

Chapter 14

Equilibria in Acid-Base Solutions

Chapter 15

Complex lon and Precipitation Equilibria

Chapter 16

Spontaneity of Reaction

Chapter 17

Electrochemistry

Chapter 18

Nuclear Reactions

Chapter 19

Complex lons

Chapter 20

Chemistry of the Metals

Chapter 21

Chemistry of the Nonmetals

Chapter 22

Organic Chemistry

Chapter 23

Organic Polymers, Natural and Synthetic

Popular Video Solutions

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Problem 1

Titanium is a metal used in jet engines. Its specific heat is $0.523 \mathrm{~J} / \mathrm{g} \cdot{ }^{\circ} \mathrm{C}$. If $5.88 \mathrm{~g}$ of titanium absorb $4.78 \mathrm{~J}$, what is the change in temperature?

Pronoy Sinha

Pronoy Sinha   Numerade Educator

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Problem 2

Two basic laws of chemistry are the law of conservation of mass and the law of constant composition. Which of these laws (if any) do the following statements illustrate? (a) Lavoisier found that when mercury(II) oxide, $\mathrm{HgO}$, decomposes, the total mass of mercury $(\mathrm{Hg})$ and oxygen formed equals the mass of mercury(II) oxide decomposed. (b) Analysis of the calcium carbonate found in the marble mined in Carrara, Italy, and in the stalactites of the Carlsbad Caverns in New Mexico gives the same value for the percentage of calcium in calcium carbonate. (c) Hydrogen occurs as a mixture of two isotopes, one of which is twice as heavy as the other.

Dr.  Satish  Ingale

Dr. Satish Ingale   Numerade Educator

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Problem 3

Gold has a specific heat of $0.129 \mathrm{~J} / \mathrm{g} \cdot{ }^{\circ} \mathrm{C}$. When a $5.00-\mathrm{g}$ piece of gold absorbs $1.33 \mathrm{~J}$ of heat, what is the change in temperature?

Pronoy Sinha

Pronoy Sinha   Numerade Educator

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Problem 4

One chocolate chip used in making chocolate chip cookies has a mass of $0.324 \mathrm{~g}$. (a) How many chocolate chips are there in one mole of chocolate chips? (b) If a cookie needs 15 chocolate chips, how many cookies can one make with a billionth $\left(1 \times 10^{-9}\right)$ of a mole of chocolate chips? (A billionth of a mole is scientifically known as a nanomole.)

Margarita Fong

Margarita Fong   Numerade Educator

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Problem 5

Classify each of the following as element, compound, or mixture. (a) air (b) iron (c) soy sauce (d) table salt

Narayan Hari

Narayan Hari   Numerade Educator

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Problem 6

Benzene, a known carcinogen, was once widely used as a solvent. A sample of benzene vapor in a flask of constant volume exerts a pressure of $325 \mathrm{~mm} \mathrm{Hg}$ at $80^{\circ} \mathrm{C}$. The flask is slowly cooled. (a) Assuming no condensation, use the ideal gas law to calculate the pressure of the vapor at $50^{\circ} \mathrm{C} ;$ at $60^{\circ} \mathrm{C}$. (b) Compare your answers in (a) to the equilibrium vapor pressures of benzene: $269 \mathrm{~mm} \mathrm{Hg}$ at $50^{\circ} \mathrm{C}$, $389 \mathrm{~mm} \mathrm{Hg}$ at $60^{\circ} \mathrm{C}$ (c) On the basis of your answers to (a) and (b), predict the pressure exerted by the benzene at $50^{\circ} \mathrm{C}$; at $60^{\circ} \mathrm{C}$.

Eileen Sullivan

Eileen Sullivan   Numerade Educator

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