Book cover for Chemistry Principles and Reactions

Chemistry Principles and Reactions

William L. Masterton, Cecile N. Hurley

ISBN #9781305079373

8th Edition

1,898 Questions

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Summary

Learning Objectives

Key Concepts

Example Problems

Explanations

Common Mistakes

Summary

This textbook section covers the core principles of gaseous chemical equilibrium, including how to write and interpret equilibrium constant expressions (K) and the reaction quotient (Q). It emphasizes the use of ICE tables to determine the pressures or concentrations at equilibrium and illustrates the predictive power of Le Châtelier’s principle in response to changes in reaction conditions such as pressure, volume, and temperature. The rules for modifying K when coefficients change (coefficient rule, reciprocal rule, and the rule for multiple equilibria) form the foundation for understanding equilibrium in both homogeneous and heterogeneous systems.

Learning Objectives

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Key Concepts

CONCEPT

DEFINITION

pH and pKa calculations

Covers the fundamental concepts of acid–base equilibria. This section introduces both the Arrhenius and Lewis definitions, explains critical parameters (pH, pKa, Ka, and Kb), and outlines the operation of buffers and the analysis of titration data.

Example Problems

Example 1

The following data are for the system $$ \mathrm{A}(g) \rightleftharpoons 2 \mathrm{~B}(g) $$ $$ \begin{array}{lcccccc} \hline \text { Time (s) } & 0 & 20 & 40 & 60 & 80 & 100 \\ P_{\mathrm{A}}(\text { atm }) & 1.00 & 0.83 & 0.72 & 0.65 & 0.62 & 0.62 \\ P_{\text {B }} \text { (atm) } & 0.00 & 0.34 & 0.56 & 0.70 & 0.76 & 0.76 \\ \hline \end{array} $$ (a) How long does it take the system to reach equilibrium? (b) How does the rate of the forward reaction compare with the rate of the reverse reaction after $30 \mathrm{~s}$ ? After $90 \mathrm{~s}$ ?

Example 2

The following data are for the system $$ \mathrm{A}(g) \rightleftharpoons 2 \mathrm{~B}(g) $$ $$ \begin{array}{lcccccc} \hline \text { Time (s) } & 0 & 30 & 45 & 60 & 75 & 90 \\ P_{\mathrm{A}} \text { (atm) } & 0.500 & 0.390 & 0.360 & 0.340 & 0.325 & 0.325 \\ P_{\text {B }} \text { (atm) } & 0.000 & 0.220 & 0.280 & 0.320 & 0.350 & 0.350 \\ \hline \end{array} $$ (a) How long does it take the system to reach equilibrium? (b) How does the rate of the forward reaction compare with the rate of the reverse reaction after $45 \mathrm{~s}$ ? After $90 \mathrm{~s}$ ?

Example 3

Complete the table below for the reaction $$ \begin{array}{c} 2 \mathrm{~A}(g)+\mathrm{B}(g) \longrightarrow 3 \mathrm{C}(g) \\ \mathrm{A}+\mathrm{B} \longrightarrow \text { products } \end{array} $$

Example 4

Complete the table below for the reaction: $$ 3 \mathrm{~A}(g)+\mathrm{B}(g) \rightleftharpoons 2 \mathrm{C}(g) $$

Example 5

Write the equilibrium expressions $(K)$ for the following reactions: (a) $\mathrm{CH}_{4}(g)+\mathrm{H}_{2} \mathrm{O}(l) \rightleftharpoons \mathrm{CO}(g)+3 \mathrm{H}_{2}(g)$ (b) $4 \mathrm{NH}_{3}(g)+5 \mathrm{O}_{2}(g) \rightleftharpoons 4 \mathrm{NO}(g)+6 \mathrm{H}_{2} \mathrm{O}(g)$ (c) $\mathrm{BaCO}_{3}(s) \rightleftharpoons \mathrm{BaO}(s)+\mathrm{CO}_{2}(g)$ (d) $\mathrm{NH}_{3}(g)+\mathrm{HCl}(g) \rightleftharpoons \mathrm{NH}_{4} \mathrm{Cl}(s)$

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