Book cover for Chemistry Principles and Reactions

Chemistry Principles and Reactions

William L. Masterton, Cecile N. Hurley

ISBN #9781305079373

8th Edition

1,898 Questions

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Summary

Learning Objectives

Key Concepts

Example Problems

Explanations

Common Mistakes

Summary

Chapter 22 covers the fundamentals of organic chemistry, focusing on the classification of organic compounds such as saturated and unsaturated hydrocarbons and aromatic compounds. It details the IUPAC nomenclature system, explores different types of isomerism including structural, geometric, and optical isomerism, and explains the roles of various functional groups. The chapter also introduces the basic organic reactions—addition, elimination, condensation, and substitution—and ties these reactions to practical applications such as fuel processing, drug synthesis, and industrial production of everyday chemicals.

Learning Objectives

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Key Concepts

CONCEPT

DEFINITION

pH and pKa calculations

Covers the fundamental concepts of acid–base equilibria. This section introduces both the Arrhenius and Lewis definitions, explains critical parameters (pH, pKa, Ka, and Kb), and outlines the operation of buffers and the analysis of titration data.

Example Problems

Example 1

Classify each of the following hydrocarbons as alkanes, alkenes, or alkynes. (a) $\mathrm{C}_{6} \mathrm{H}_{14}$ (b) $\mathrm{C}_{3} \mathrm{H}_{4}$ (c) $\mathrm{C}_{9} \mathrm{H}_{18}$

Example 2

Classify each of the following hydrocarbons as alkanes, alkenes, or alkynes. (a) $\mathrm{C}_{12} \mathrm{H}_{24}$ (b) $\mathrm{C}_{7} \mathrm{H}_{12}$ (c) $\mathrm{C}_{13} \mathrm{H}_{28}$

Example 3

Write the formula for (a) an alkene with two carbon atoms. (b) an alkane with 22 hydrogen atoms. (c) an alkyne with three carbon atoms.

Example 4

Write the formula for (a) an alkyne with 16 hydrogen atoms. (b) an alkene with 44 hydrogen atoms. (c) an alkane with ten carbon atoms.

Example 5

Name the following alkanes.

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Step-by-Step Explanations

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Common Mistakes

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