Book cover for Materials Science and Engineering: An Introduction

Materials Science and Engineering: An Introduction

William D. Callister, Jr. David G. Rethwisch

ISBN #9780471736967

7th Edition

771 Questions

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Summary

Learning Objectives

Key Concepts

Example Problems

Explanations

Common Mistakes

Summary

This section covers the essential principles of polymer structure and chemistry. It explains how polymers form from repeated monomer units, describes methods for representing and calculating molecular weights and degree of polymerization, and discusses various structural configurations including linear, branched, crosslinked, and network forms. The section further distinguishes between stereochemical arrangements, thermoplastic versus thermosetting behaviors, and outlines crystallinity and diffusion phenomena in polymers. Understanding these concepts provides a foundation for predicting and tailoring polymer properties for diverse applications.

Learning Objectives

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Key Concepts

CONCEPT

DEFINITION

Ceramics Fabrication Techniques

The methods and processes used for shaping, forming, and consolidating ceramic materials into final products with desired properties.

Example Problems

Example 1

On the basis of the structures presented in this chapter, sketch repeat unit structures for the following polymers: (a) polychlorotrifluoroethylene, and (b) poly(vinyl alcohol).

Example 2

Compute repeat unit molecular weights for the following: (a) polytetrafluoroethylene (b) poly(methyl methacrylate), (c) nylon 6,6 and (d) poly(ethylene terephthalate)

Example 3

The number-average molecular weight of a polystyrene is $500,000 \mathrm{g} / \mathrm{mol}$. Compute the degree of polymerization.

Example 4

(a) Compute the repeat unit molecular weight of polypropylene. (b) Compute the number-average molecular weight for a polypropylene for which the degree of polymerization is 15,000

Example 5

Below, molecular weight data for a polytetrafluoroethylene material are tabulated. Compute (a) the number-average molecular weight, (b) the weight-average molecular weight, and (c) the degree of polymerization.

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Step-by-Step Explanations

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Common Mistakes

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