A close analogy exists between the flow of energy by heat because of a temperature difference (see Section 19.6 ) and the flow of electric charge because of a potential difference. In a metal, energy $d Q$ and electrical charge $d q$ are both transported by free electrons. Consequently, a good electrical conductor is usually a good thermal conductor as well. Consider a thin conducting slab of thickness $d x,$ area $A$, and electrical conductivity $\sigma$, with a potential difference $d V$ between opposite faces. (a) Show that the current $I=d q / d t$ is given by the equation on the left:
Charge conduction
$$
\frac{d q}{d t}=\sigma A\left|\frac{d V}{d x}\right|
$$
Thermal conduction
$$
\frac{d Q}{d t}=k A\left|\frac{d T}{d x}\right|
$$
In the analogous thermal conduction equation on the right (Eq. 19.17 ), the rate $d Q / d t$ of energy flow by heat (in SI units of joules per second) is due to a temperature gradient $d T / d x$ in a material of thermal conductivity $k$. (b) State analogous rules relating the direction of the electric current to the change in potential and relating the direction of energy flow to the change in temperature.