00:01
Okay, in this problem we have a liquid cesium sample that we're superheating to produce an atomic beam of some kind.
00:09
It's kind of interesting.
00:10
The temperature of our oven is about 400 degrees celsius, and it's about 55 cubic centimeters.
00:16
The vapor pressure of the cesium will be 17 millimeters mercury, and we're given the diameter of the cesium atoms, which is about 0 .33 nanometers.
00:26
In parts a, b, and c, we're asked to find respectively the root mean square velocity, which we can just, get from kinetic theory and then we're asked to find the frequency that an individual atom collides with other atoms so that we're going to call that f sub c and then we're asked in part c to find the total frequency of all the atoms colliding per second so a number of collisions per second total in our sample okay so to start us off the root mean square velocity is given from kinetic theory it's root 3k t over m where k is boltzman's constant we have the temperature of our sample and m is the mass of the individual atoms.
01:11
An equivalent expression is root 8 kt over pi m which is this is equation 18 -7b.
01:32
So just plugging everything in we have remember our bolstman constant is one always 1 .38 times 10 the negative 23 joules per kelvin the temperature in kelvin and sv in kelvin 670, kelvin, that's just 400 plus 273, which is how we do the conversion.
01:53
So we have pi times 133 times 1 .66 times 10 to negative 27 kilograms.
02:03
Okay? and crunching the numbers, the root mean square velocity will come out to be about 330 meters per second.
02:17
It's actually 327 .3, but it's good to approximate it up to something nice.
02:21
All right.
02:24
Now to get a collision frequency, we need to get the mean -free path, which is the distance a individual animal travel before it makes a collision.
02:36
We'll combine this with the ideal gas law.
02:41
So to start, the ideal gas law, pv equals big n kt, and it's a total number of particles in the gas.
02:48
K is both means constant as usual.
02:50
We need to get n over v, which is p over kt.
02:56
We're going to use this for later because the traditional.
02:58
Expression for mean -free path involves n over v and that actual expression is kind of gross to be honest 1 over 4 pi root 2 r squared where r is the radius of the individual particles times n over v which you can see we're going to replace n over v by something involving pressure and temperature instead and so once we make that substitution we get kt over 4 pi root 2 r squared times p all right at this point, we can plug in boltzman's constant, temperature, the radius of our particles, which we're given, and the pressure, which we're also given in millimeters mercury.
03:51
So it's actually, it probably would be useful to actually put these numbers in because there's a little bit of nuance in how we're doing these units.
03:57
It gets a little gross.
04:00
Boltzman's constant is as usual.
04:03
Temperature is as usual for pi root two.
04:11
Remember, the radius is half the diameter.
04:13
That's a common mistake, because we have to use half.
04:16
1 .65 times 10 to the negative 10 meters squared.
04:24
Our pressure 17 millimeters mercury needs to be converted into pascales, which is 133.
04:33
Sorry, i'm almost out of space here.
04:36
133 pascales per 1 millimeter mercury.
04:41
I'm not going to include that...