(a) Why would you not expect to observe an IR spectroscopic absorption for the $\mathrm{C} \equiv \mathrm{C}$ stretch of $\mathrm{C}_{2} \mathrm{H}_{2} ?$ (b) Would you expect to observe such an absorption in the IR spectrum of $\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{C} \equiv \mathrm{CH} ?$