Among the following pairs of compounds, the one that illustrates the law of multiple proportions is
(a) $\mathrm{Cu}$ and $\mathrm{CuSO}_{4}$
(b) $\mathrm{CuO}$ and $\mathrm{Cu}_{2} \mathrm{O}$
(c) $\mathrm{H}_{2} \mathrm{~S}$ and $\mathrm{SO}_{2}$
(d) $\mathrm{NH}_{3}$ and $\mathrm{NCl}_{3}$