An air sample contains $1.89 \times 10^{-4} \%$ of methane gas (CH $_{4}$ ). The Henry's law constant for methane in water is approximately $1.3 \times 10^{-3} \mathrm{M}$ at $20^{\circ} \mathrm{C}$ and 1.0 atm.
a. Calculate the solubility of methane in water under a pure methane atmosphere of 1.0 atm.
b. Calculate the maximum solubility of the methane found in the air sample.