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Approximately 0.14$\quad \mathrm{g}$ of nickel(II) hydroxide, $\mathrm{Ni}(\mathrm{OH})_{2}(s),$ dissolves per liter of water at $20^{\circ} \mathrm{C}$ . Calculate $K_{\mathrm{sp}}$ for $\mathrm{Ni}(\mathrm{OH})_{2}(s)$ at this temperature.
$K_{\mathrm{sp}}=1.35 \times 10^{-8}$
Chemistry 102
Chapter 17
Equilibrium
Section 9
Solubility Equilibria
Chemical Equilibrium
Rice University
Drexel University
University of Maryland - University College
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So in this question we're looking at, um, the dissociation of nickel hydroxide, um, nickel to hydroxide, to be specific, just solid to become the nickel two plus ion and to hydroxide ions, which are both, uh, acquis. I'm just having a just traded up here so we don't take this now, we're going to work through this all symbolically and then just plugging numbers is so we're gonna do a nice table to represent the, uh, amount of yeah, that we're gonna have a nickel and hydroxide adequate. So we have I see initial change in equilibrium. We ignore solids for this. So doesn't matter what's over here. Initially, we don't have effectively zero concentration of either of these that we're gonna have a change, which is gonna be plus acts. And plus two X, which comes from the fact that for every single mole of nickel hydroxide that dissolves, we're gonna get a mole of nickel and two moles of hydroxide and that Saudi government of X and two X. So in a different color, we're gonna write out the mass actions fresh. Now, remember, the mass action expression is equal to the concentrations of the products here And since we're ignoring this, we always go in solids. In the mass action expression, there's really nothing in our genome air, nothing for the react. So we're gonna have nickel two plus times a concentration of hydroxide squared which comes from the coefficient to here. And so if we plug in this X for nickel and two X for hydroxide will get X times two x squared, which equals four. Execute. So this is we're trying to find CASS. Be if we can figure out X that fantastic and were given acts just indirectly works hold different color here. We're told that we have 0.14 grams of nickel hydroxide. And so if we could figure out how many moles of nickel hydra because we have that much that dissolves in water Actually, Mom, about that we have 0.14 grams of dissolves in water. So what that means is we can figure out how many moles of that that is. Then we can figure out how many moles of nickel hydroxide dissolved in water, which also is you to be equal to the moors of nickel two plus that's dissolved in water, which is equal to acts. And so we need to, uh, divide, uh, 12.14 by the molten black lor weight of nickel hydroxide, which is 92.7 grams per mole. And we'll get some amount, which is equal to 1.51 times 10 to negative third moles. And that's equal to acts like I just described. And so now, if you plug in that value for four execute, you'll get that Casspi is equal to 1.3 seven times 10 to the negative eighth, and that's our final.
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