Question

Calculate $\Delta G$ in the preparation of 1000 ml of 2.0 M $\mathrm{HClO}_4$ solution, assuming ideal mixing and that each ion contributes individually to the entropy, at 298 K .

   Calculate $\Delta G$ in the preparation of 1000 ml of 2.0 M $\mathrm{HClO}_4$ solution, assuming ideal mixing and that each ion contributes individually to the entropy, at 298 K .
Physical Chemistry : Thermodynamics, Statistical Mechanics & Kinetics
Physical Chemistry : Thermodynamics, Statistical Mechanics & Kinetics
Andrew Cooksy 1st Edition
Chapter 9, Problem 34 ↓
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Calculate $\Delta G$ in the preparation of 1000 ml of 2.0 M $\mathrm{HClO}_4$ solution, assuming ideal mixing and that each ion contributes individually to the entropy, at 298 K .
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Transcript

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00:01 In order to answer this question, let's recall our equation for delta g that involves a k constant.
00:13 So that equation is going to be delta g is equal to negative rt and times the natural log of k.
00:26 In this case, k that we're going to be looking for is going to be k.
00:33 K -a -1.
00:36 K -a -1 is the acid dissociation constant of h -c -l -o, and we know that we're going to be looking for this k -a, because the reaction that we are looking at, which is h -c -l -o plus water, becomes h -3 -o -0 plus and c -l -o -minus.
01:28 And this is the same equation that gets defined by k -a -1 of h -c -l -o.
01:38 As you can see, the hydrogen from the acid goes to the water, makes the hydronium ion, which is characteristic of an acid, and it leaves behind a conjugate base.
01:56 So we can write below our conjugate base and our conjugate acid...
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