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Calculate the formal charge on each second-row atom:
a. The formal charge on $N$ atom is $+1 .$b. The formal charge on $N$ atom is $+1,$ on the first $C$ atom is 0 and on thesecond $C$ atom is $-1$ .c. The formal charge on the first $\mathrm{O}$ atom is $0,$ on the second is $+1$ and onthe third is $-1 .$
Organic Chemistry
Chapter 1
Structure and Bonding
Section 3
Lewis Structures
Introduction to organic chemistry
Millikin University
Masinde Muliro University of Science and Technology
Lectures
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04:40
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calculate the formal charge on each second row. Adam. So the second row Adams are boron, carbon, nitrogen often florian and neon. I suppose I would also consider live human brilliant, but were not given either of those. So we have to calculate the formal charge on the nitrogen, carbon, nitrogen, carbon, oxygen, oxygen, oxygen. We don't have to worry about the formal charges on hydrogen. So to start the formula for calculating form charge is the number of valence electrons in the number of electrons that the Adam brings in. Minus the number of electrons it owns currently gives you the formal charge. So the hardest part is figuring out how many electrons thie Adam currently owns. Let's start with this ammonium species, so we're looking at the nitrogen to determine how many electrons it owns. What you can do is split each bond it has in half. So hear this nitrogen. If you split the hydrogen nitrogen bomb in half, give one electron the nitrogen oneto, hydrogen that leaves just one electron of this bond to nitrogen. Same here. This nitrogen hydrogen bonds split it in half. One electron goes to hydrogen. One electron goes to nitrogen. If we do that for all of these bonds and add up the number of electrons still around nitrogen, you get one, two, three, four. So the number of violence minus the number it currently owns gives us five valence electrons because it was in group five, minus four electrons from splitting all the bonds and half gives us plus one. Therefore, nitrogen must have a formal positive charge. For the second example here, they didn't draw out the carbon hydrogen bonds. So, Justus, a general rule of thumb, go ahead and draw out the Louis structure if you don't readily see it. So draw in those carbon hydrogen bonds so you can calculate the number of owned electrons. It will always give you the right answer. So split those bonds and half just to figure out the formal charge around this carbon. So violence carbon comes in in groups for a so it has four valence electrons. If we split each of these bonds of half, give one electron in a hydrogen when electron to carbon one electron in a hydrogen one the carbon oneto hydrogen one to carbon one to carbon one to nitrogen. So this works with bonds that aren't just hydrogen carbon as well. It's for any bond in general. So this carbon currently has one, two, three, four electrons when he split e to the bonds and half. So for valence electrons coming in minus the four and splitting the bonds and half the number of owned electrons gives us zero. So there is no formal charge on that carbon. Let's take a look at the nitrogen. So if we split a triple bond in half, that is splitting every single bond of the triple bomb it half. So one electron from this pond goes to nitrogen. One from this bongos to nitrogen. One from this bond goes to nitrogen, and then one from each of these goes to carbon. And so, where you have to count up all three of these bonds gives us three electrons here, one here, So it is owning. Currently, four electrons now nitrogen came in with five. So five valence electrons minus the one two three four at currently owns tells us that nitrogen currently has a formal plus one charge. It is missing an electron. Now, if you look at carbon, they also tell you there's a lone pair of electrons on this carbon splitting this bond, this triple bonded half gives us one, two, three electrons. You also count loan pears. The entire loan pair is counted into the owned number of electrons, so one, two three four five owned electrons is how many this carbon currently has. Now carbon comes in with four because it's in group for a for violence. Electrons minus defy that currently have tells us the nitrogen or carbon has a formal negative charge in this compound, moving down to the oxygen species simply split these bonds, and half this oxygen came in with six electrons. Sex violence minus one, two, three, four, five six So six balance minus six owned gives us a formal charge of zero, so no plus and minus charged. Looking at the central oxygen, oxygen again comes in with six valence electrons minus one two three four five Tells us this oxygen has a formal plus one charge
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